Sulfur: Difference between revisions

iso	NA	half-life	DM	DE M eV	DP
³²S	95.02%	S is stable with 16 neutrons
³³S	0.75%	S is stable with 17 neutrons
³⁴S	4.21%	S is stable with 18 neutrons
³⁵S	{syn.}	87.32 d	β^-	0.167	³⁵Cl
³⁶S	0.02%	S is stable with 20 neutrons

SI units & STP are used except where noted.

Sulfur (or Sulphur; see spelling below) is the chemical element in the periodic table that has the symbol S and atomic number 16. An abundant, tasteless, odorless, multivalent, non-metal, sulfur, in its native form, is a yellow crystaline solid. Sulfur, in nature, can be found in its native form or as sulfide and sulfate minerals. It is an essential element for life and is found in several amino acids. Its commercial uses are primarily fertilizers but it is also widely used in gunpowder, laxatives, matches, insecticides and fungicides.

Notable characteristics

This non-metal is a soft and light substance, pale yellow in appearance. Although hydrogen sulfide (H₂S) has a distinct smell of rotten eggs, it should be noted that elemental (yellow) sulphur is odorless. It burns with a blue flame that emits sulfur dioxide, notable for its peculiar suffocating odor. Sulfur is insoluble in water but soluble in carbon disulfide. Common oxidation states of sulfur include −2, +2, +4 and +6. Sulfur forms stable compounds with all elements except the noble gases.

Sulfur ordinarily exists as molecules in the solid state, mainly adopting a cyclic crown-shaped S₈. The S₈ structure is easily represented on paper by writing two W letters of different sizes, with their ends connected on each side: each corner represents a S atom. The three dimensional arrangement of atoms can be thought of of as two squares offset by 45° and stacked on top of one another so that one square rests in the gaps made by the other square. Sulfur has many allotropes besides S₈. Removing one atom from the crown gives S₇, which is responsible for the bright yellow color associated with sulfur. Many other rings have been prepared, including S₁₂ and S₁₈.

The crystallography of sulfur is complex. Depending on the specific conditions, the sulfur allotropes form several distinct crystal structures, with rhombic and monoclinic S₈ best known. By contrast, its lighter neighbor oxygen only exists in two states of chemical significance: O₂ and O₃ (ozone, with a structure resembling that of SO₂). Selenium, the heavier analogue of sulfur, forms a few rings but is more stable as a gray polymer.

A noteworthy property is that the viscosity of molten sulfur, unlike most other liquids, increases with temperature due to the formation of polymers.

Amorphous or "plastic" sulfur can be produced through the rapid cooling of molten sulfur. X-ray crystallography studies show that the amorphous form may have a helical structure with eight atoms per turn. This form is metastable at room temperature, however, and gradually reverts back to crystalline form. This process happens within a matter of hours to days but can be rapidly catylized by human saliva (NOTE: never place sulfur or any of its compounds in the mouth).

Applications

Sulfur has many industrial uses. Through its major derivative, sulfuric acid (H₂SO₄), sulfur ranks as one of the more-important elements used as an industrial raw material. It is of prime importance to every sector of the world's industrial and fertilizer complexes. Sulfuric acid production is the major end use for sulfur, and consumption of sulfuric acid has been regarded as one of the best indexes of a nation's industrial development. More sulfuric acid is produced in the United States every year than any other chemical. Sulfur is also used in batteries, detergents, gunpowder, and the vulcanization of rubber. Sulfur is used as a fungicide, and in the manufacture of phosphate fertilizers. Sulfites are used to bleach papers and dried fruits. Sulfur also finds use in matches and fireworks. Sodium or ammonium thiosulfate are used as photographic fixing agents. Epsom salts, magnesium sulfate, can be used as a laxative, as a bath additive, as an exfoliant, or a magnesium supplement in plant nutrition.

Biological role

The amino acids cysteine and methionine contain sulfur, as do all polypeptides, proteins, and enzymes which contain these amino acids making sulfur a necessary component of all living cells. Disulfide bonds between polypeptides are very important in protein assembly and structure. Homocysteine and taurine are also sulfur containing amino acids but are not coded for by DNA or part of the primary structure of proteins. Some forms of bacteria use hydrogen sulfide (H₂S) in the place of water as the electron donor in a primitive photosynthesis-like process. Sulfur is absorbed by plants from soil as sulfate ion. Inorganic sulfur forms a part of iron-sulfur clusters, and sulfur is the bridging ligand in the Cu_A site of cytochrome c oxidase. Sulfur is an important component of coenzyme A

Enviromental Impact

The massive burning of coal by industry and power plants liberates huge amounts of sulfur dioxide SO₂, which reacts with atmospheric water and oxygen to produce sulfuric acid. This causes acid rain which lowers the pH of soil and freshwater bodies, resulting in substantial damage to the natural environment in some regions.

History

File:SulfurCrystalUSGOV.jpg

Sulfur crystal

Sulfur (Sanskrit, sulvere; Latin sulpur) was known in ancient times, and is referred to in the Biblical story of Pentateuch (Genesis). English translations of this commonly refer to sulfur as "brimstone", giving rise to the name of 'Fire and brimstone' sermons, which are sermons where hell and eternal damnation for sinners is stressed. It is from this part of the bible that hell is thought to smell of sulfur. The word itself is almost certainly from the Arabic "sufra" meaning yellow, from the bright color of the naturally-occurring form. If there is indeed a Sanskrit word 'sulvere', this can only be a borrowing. Homer mentioned "pest-averting sulfur" in the 9th century BC and in 424 BC, the tribe of Bootier destroyed the walls of a city by burning a mixture of coal, sulfur, and tar under them. Sometime in the 12th century, the Chinese invented gun powder which is a mixture of potassium nitrate (K N O₃), carbon, and sulfur. Early alchemists gave sulfur its own alchemical symbol which was a triangle at the top of a cross. Through experimentation, alchemists knew that the element mercury can be combined with sulfur. In the late 1770s, Antoine Lavoisier helped convince the scientific community that sulfur was an element and not a compound. In 1867 sulfur was discovered in underground deposits in Louisiana and Texas. The overlying layer of earth was quicksand, prohibiting ordinary mining operations. Therefore the Frasch process was utilized.

Occurrence

Sulfur occurs naturally in large quantities compounded to other elements in sulfides (example: pyrite) and sulfates (example: gypsum). It is found in its free form near hot springs and volcanic regions (hence the name brimstone, from being found at the brim of craters) and in ores like cinnabar, galena, sphalerite and stibnite. This element is also found in small amounts in coal and petroleum, which produce sulfur dioxide when burned. Fuel standards increasingly require sulfur to be extracted from fossil fuels because sulfur dioxide combines with water droplets to produce acid rain. This extracted sulfur is then refined and represents a large portion of sulfur production. It is also mined along the US Gulf coast by the Frasch process, which involves pumping a mixture of compressed air and superheated water into sulfur containing deposits (such as salt domes). The hot water melts the sulfur, and the pressure of the air drives the molten sulfur to the surface.

The distinctive colors of Jupiter's volcanic moon Io, are from various forms of molten, solid and gaseous sulfur. There is also a dark area near the Lunar crater Aristarchus that may be a sulfur deposit. Sulfur is also present in many types of meteorites.

Compounds

Hydrogen sulfide, has the characteristic smell of rotten eggs. Dissolved in water, hydrogen sulfide is acidic (pK_a1 = 7.00, pK_a2 = 12.92) and will react with metals to form a series of metal sulfides. Natural metal sulfides are found, especially those of iron. Iron sulfides are called iron pyrite, the so called fool's gold. Interestingly, pyrite can show semiconductor properties.[1] Galena, a naturally occurring lead sulfide, was the first semiconductor discovered, and found a use as a signal rectifier in the early "cat's whisker" (crystal radios)

Many of the unpleasant odors of organic matter are based on sulfur-containing compounds such as ethyl and methyl mercaptan used to scent natural gas so that leaks are easily detectable. The odor of garlic and "skunk stink" are also caused by sulfur containing organic compounds.

Polymeric sulfur nitride has metallic properties even though it doesn't contain any metal atoms. This compound also has unusual electrical and optical properties.

Other important compounds of sulfur include:

sodium dithionite, Na₂S₂O₄, a powerful reducing agent.
sulfurous acid, H₂SO₃, created by dissolving SO₂ in water. Sulfurous acid and the corresponding sulfites are fairly strong reducing agents. Other compounds derived from SO2 include the pyrosulfite ion (S₂O₅^2-).
The thiosulfates (S₂O₃^2-). Thiosulfates are used in photographic fixing, are oxidizing agents, and ammonium thiosulfate is being investigated as a cyanide replacement in leaching gold.[2]
Compounds of dithionic acid (H₂S₂O₆)
The polythionic acids, (H₂S_nO₆), where n can range from 3 to 80.
The sulfates, the salts of sulfuric acid. Epsom salts are magnesium sulfate.
Sulfides are simple compounds of sulfur with some other chemical element.
Sulfuric acid reacts with SO₃ in equimolar ratios forms pyrosulfuric acid.
peroxymonosulfuric acid and peroxydisulfuric acids, made from the action of SO₃ on concentrated H₂O₂, and H₂SO₄ on concentrated H₂O₂ respectively.
tetrasulfur tetranitride S₄N₄.
Thiocyanates are compounds containing the thiocyanate ion, SCN^-
thiocyanogen, (SCN)₂.
A thioether is a molecule with the form R-S-R', where R and R' are organic groups. These are the sulfur equivalents of ethers.
A thiol (also known as a mercaptan) is a molecule with an -SH functional group. These are the sulfur equivalents of alcohols.
A thiolate ion has an -S^- functional group attached. These are the sulfur equivalent of alkoxide ions.
A sulfone is a molecule with an R-S(=O)-R' functional group where R and R' are organic groups.
A sulfoxide is a molecule wiht an R-S(=O)(=O)-R' functional group where R and R' are organic groups. A common example of a sulfoxide is DMSO.

Isotopes

Sulfur has 18 isotopes, of which four are stable: ³²S (95.02%), ³³S (0.75%), ³⁴S (4.21%), and ³⁶S (0.02%). Other than ³⁵S, the radioactive isotopes of sulfur are all short lived. Sulfur-35 is formed from cosmic ray spallation of argon-40 in the atmosphere. it has a half-life of 87 days.

When sulfide minerals are precipitated, isotopic equilibration among solids and liquid may cause small differences in the dS-34 values of co-genetic minerals. The differences between minerals can be used to estimate the temperature of equilibration. The dC-13 and dS-34 of co-existing carbonates and sulfides can be used to determine the pH and oxygen fugacity of the ore-bearing fluid during ore formation.

In most forest ecosystems, sulfate is derived mostly from the atmosphere; weathering of ore minerals and evaporites also contributes some sulfur. Sulfur with a distinctive isotopic composition has been used to identify pollution sources, and enriched sulfur has been added as a tracer in hydologic studies. Differences in the natural abundances can also be used in systems where there is sufficient variation in the S-34 of ecosystem components. Rocky Mountain lakes thought to be dominated by atmospheric sources of sulfate have been found to have different dS-34 values from lakes believed to be dominated by watershed sources of sulfate.

Precautions

Carbon disulfide, hydrogen sulfide, and sulfur dioxide should all be handled with care.

Although sulfur dioxide is sufficiently safe to be used as a food additive in small amounts, in higher atmospheric concentration it reacts with water in the lungs to form sulfurous acid there; this causes immediate bleeding, the lungs fill up with blood and suffocation results. In creatures without lungs such as insects or plants, it otherwise prevents respiration.

Hydrogen sulfide is quite toxic (more toxic than cyanide). Although very smelly at first, it quickly deadens the sense of smell, so potential victims may be unaware of its presence until it is too late.

Spelling

The element has traditionally been spelled sulphur in the United Kingdom, India, and New Zealand, but sulfur in the United States, while both spellings are used in Australia and Canada. The IUPAC has adopted the spelling "sulfur", as has the Royal Society of Chemistry Nomenclature Committee.

References

Los Alamos National Laboratory – Sulfur

External links

@@ Line 149: / Line 149: @@
 |}
-'''Sulfur''' (or '''Sulphur'''; see [[#Spelling|spelling]] below) is the [[chemical element]] in the [[periodic table]] that has the symbol '''S''' and [[atomic number]] 16. An abundant tasteless odorless multivalent [[non-metal]], sulfur is best known as yellow crystals and occurs as [[sulfide]] and [[sulfate]] minerals and even in its native form (especially in [[volcano|volcanic]] regions). It is an essential element in all living organisms and is needed in several [[amino acid]]s and hence in many [[protein]]s. It is primarily used in [[fertilizer]]s but is also widely used in [[gunpowder]], [[laxative]]s, [[match]]es,  [[insecticide]]s and [[fungicide]]s.
+'''Sulfur''' (or '''Sulphur'''; see [[#Spelling|spelling]] below) is the [[chemical element]] in the [[periodic table]] that has the symbol '''S''' and [[atomic number]] 16. An abundant, tasteless, odorless, multivalent, [[non-metal]], sulfur,  in its native form,  is a yellow crystaline solid.  Sulfur,  in nature,  can be found in its native form or as [[sulfide]] and [[sulfate]] minerals.  It is an essential element for life and is found in several [[amino acid]]s.  Its commercial uses are primarily [[fertilizer]]s but it is also widely used in [[gunpowder]], [[laxative]]s, [[match]]es,  [[insecticide]]s and [[fungicide]]s.
 == Notable characteristics ==

Revision as of 03:25, 21 March 2005