Lutetium acetylacetonate

Lutetium acetylacetonate
	File:Tris(acetylacetonato)lutetium.png
Identifiers
CAS Number	17966-84-6 ;
Properties
Chemical formula	C15H21LuO6
Molar mass	472.294 g·mol−1
	Except where otherwise noted, data are given for materials in their standard state (at 25 °C [77 °F], 100 kPa). Infobox references

Lutetium acetylacetonate is a coordination compound with the chemical formula Lu(C₅H₇O₂)₃, or Lu(acac)₃ for short. It is isomorphic to ytterbium acetylacetonate.^[1] It can be prepared by the reaction of trialkoxylutetium and acetylacetone.^[2]

Its dihydrate and 1,10-Phenanthroline (phen) or 2,2'-bipyridine (dipy) are refluxed in ethanol solution to obtain mixed ligand complexes Lu(acac)₃(phen) and Lu(acac)₃(dipy).^[3]

References

^ Trembovetskii, G. V.; Martynenko, L. I.; Murav'eva, I. A.; Spitsyn, V. I. Synthesis and study of volatile rare earth acetylacetonates(in Russian). Doklady Akademii Nauk SSSR, 1984. 277 (6): 1411-1414. ISSN 0002-3264.
^ Gavrilenko, V. V.; Chekulaeva, L. A.; Savitskaya, I. A.; Garbuzova, I. A. Synthesis of yttrium, lanthanum, neodymium, praseodymium and lutetium alkoxides and acetylacetonates(in Russian). Izvestiya Akademi Nauk, Seriya Khimicheskaya, 1992. 11: 2490-2493. ISSN 1026-3500.
^ Andrey Yu. Rogachev, Andrey V. Mironov, Sergey I. Troyanov, Natalia P. Kuzmina, Alexander V. Nemukhin (May 2006). "Synthesis, crystal structures and theoretical study of mixed ligand complexes of lanthanides acetylacetonates with o-phenanthroline and 2,2′-dipyridyl: The unexpected inverted electrostatic trend in stability". Journal of Molecular Structure. 789 (1–3): 187–194. doi:10.1016/j.molstruc.2005.12.026. Archived from the original on 2020-02-25. Retrieved 2021-09-20.{{cite journal}}: CS1 maint: multiple names: authors list (link)

[1] Trembovetskii, G. V.; Martynenko, L. I.; Murav'eva, I. A.; Spitsyn, V. I. Synthesis and study of volatile rare earth acetylacetonates(in Russian). Doklady Akademii Nauk SSSR, 1984. 277 (6): 1411-1414. ISSN 0002-3264.

[2] Gavrilenko, V. V.; Chekulaeva, L. A.; Savitskaya, I. A.; Garbuzova, I. A. Synthesis of yttrium, lanthanum, neodymium, praseodymium and lutetium alkoxides and acetylacetonates(in Russian). Izvestiya Akademi Nauk, Seriya Khimicheskaya, 1992. 11: 2490-2493. ISSN 1026-3500.

[3] Andrey Yu. Rogachev, Andrey V. Mironov, Sergey I. Troyanov, Natalia P. Kuzmina, Alexander V. Nemukhin (May 2006). "Synthesis, crystal structures and theoretical study of mixed ligand complexes of lanthanides acetylacetonates with o-phenanthroline and 2,2′-dipyridyl: The unexpected inverted electrostatic trend in stability". Journal of Molecular Structure. 789 (1–3): 187–194. doi:10.1016/j.molstruc.2005.12.026. Archived from the original on 2020-02-25. Retrieved 2021-09-20.{{cite journal}}: CS1 maint: multiple names: authors list (link)

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