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Phosphination of aryl/alkyl bromides <i>via</i> Mn-mediated reductive C-P coupling.

Author information

Affiliations

  • 1. Center of Basic Molecular Science (CBMS), Department of Chemistry, Tsinghua University, Beijing 100084, China.
      Authors
    • Dong L 1
    • Zhong B 1
    • Zhang YS 1
    • Yang JD 1
    • Cheng JP 1
    (5 authors)

ORCIDs linked to this article

Chemical Communications (Cambridge, England), 24 Oct 2024, 60(86):12549-12552
https://doi.org/10.1039/d4cc04750h PMID: 39380453 

Abstract 

Mn-mediated reductive cross-coupling of organic bromides with 2-bromo-1,3,2-diazaphospholene was developed for efficient construction of C-P bonds under mild conditions. Mechanistic studies suggested that bromides are activated by in situ formed bis-diazaphospholene via hybrid radical and polar mechanisms.

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Read article at publisher's site: https://doi.org/10.1039/d4cc04750h

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Funding 

Funders who supported this work.

National Natural Science Foundation of China (4)