New naphthopyrones from marine-derived fungus Aspergillus niger 2HL-M-8 and their in vitro antiproliferative activity

Nat Prod Res. 2016;30(10):1116-22. doi: 10.1080/14786419.2015.1043553. Epub 2015 Jul 15.

Abstract

A new cytotoxic dimeric naphthopyrone, aurasperone H (1), together with eight related known polyketides (2-9) was isolated from a marine-derived fungus Aspergillus niger 2HL-M-8. The structure of new compound 1 was elucidated on the basis of its spectroscopic data (1D, 2D NMR and CD). Compound 1 exhibited moderate inhibitory activity against the human lung adenocarcinoma A549 and the human leukaemia HL-60 cell lines. Compound 5 displayed significant in vitro antiproliferative activity against HL-60 cell line with an IC50 value of 0.8 μM.

Keywords: Aspergillus niger; antiproliferative activity; dimeric naphthopyrones.

MeSH terms

  • Antineoplastic Agents / isolation & purification
  • Antineoplastic Agents / pharmacology*
  • Aspergillus niger / chemistry*
  • Cell Line, Tumor / drug effects
  • HL-60 Cells / drug effects
  • Humans
  • Magnetic Resonance Spectroscopy
  • Marine Biology
  • Molecular Structure
  • Naphthalenes / isolation & purification
  • Naphthalenes / pharmacology*
  • Polyketides / chemistry
  • Polyketides / isolation & purification
  • Pyrones / isolation & purification
  • Pyrones / pharmacology*

Substances

  • Antineoplastic Agents
  • Naphthalenes
  • Polyketides
  • Pyrones
  • aurasperone H
  • naphthopyrone dimer