Talk:Carbon dioxide: Difference between revisions
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== unclear properties values in brackets == |
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I have corrected the conversion of ppm by volume to ppm by mass. The original note claims that this conversion could be performed by multiplying by the ratio of the '''molecular masses''' of CO2 and Air. The correct equation multiplies by the ratio of the '''densities''' of CO2 and Air. The difference between the density of moist air and the density of dry air is a non-trivial factor, and so volume can not be disregarded. A quick dimensional analysis will confirm that this is the correct method: |
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(m/m)=(v/v)(m/v)(v/m) |
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⚫ | ::5.7292(30) MPa, 56.54(30) atm would translate to 5.7292 ± 0.0030 for MPa and 56.54 ± 0.30 atm but '''those are the same measurement just with different units. So the uncertainty can't be the same''' as 5.7262 MPa (-0.003) are 56.5132 atm and not 56.24 - so i conclude these are not uncertainties. (other 7.3743MPa is 72.77868 atm would work (72.778atm) as here the atm value is given with 3 decimals but even if we use 56.54(3)atm it seem to work but 56.542(30) would be 56.512 not 56.5132 as the certainty wouldn't have ⅒ but ¹/₉.₈₆₉₂₃₃ as a factor - So it is very unlikely that the MPa and atm values were from two different measurements with different uncertainties that accidentally have the same numerical value - while just a typo moved a decimal place. [[Special:Contributions/2A01:C22:CD04:2B00:98A2:90A1:EB26:C385|2A01:C22:CD04:2B00:98A2:90A1:EB26:C385]] ([[User talk:2A01:C22:CD04:2B00:98A2:90A1:EB26:C385|talk]]) 09:04, 25 August 2023 (UTC) |
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:::I completely agree. I think that we should therefore remove the numbers within the parentheses, and then try to find better sources. [[User:Qflib|Qflib, aka KeeYou Flib]] ([[User talk:Qflib|talk]]) 22:01, 25 August 2023 (UTC) |
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==Ambiguous units of measurement like "ppm" and "%" across this article== |
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Or to be more explicit: |
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There are many data with ambiguous units of measurement like "[[Parts-per notation|ppm]]" and "%" across this article (and many other articles across Wikipedia), without a clear explanation what those units stand for. Without a clear explanation, those units can stand for mass per volume, volume per volume, mole per mole or who knows what else. Can someone clarify what those units stand for, despite that is not clarified in the sources? The data about the concentrations of [[carbon dioxide]] (and other [[Inert gas asphyxiation|suffocating]] and [[toxic gas]]es and substances) in the air, water, food, drinks, products, etcetera, is a very important information for readers, especially non-expert ones, so, editors should be notified about the very existence of the ambiguous "ppm", "%" and similar ambiguous units across Wikipedia. Let's discuss. I am opening a debate. What do you think? Do you agree or disagree with me, and explain why. Thanks in advance for your opinion. [[User:Bernardirfan|Bernardirfan]] ([[User talk:Bernardirfan|talk]]) 18:08, 30 August 2023 (UTC) |
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mCO2/mAir = (vCO2/vAir) (vAir/mAir) (mCO2/vCO2) |
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Taking this approach usually gets you a ppm-m that is about 1.9 times greater than the ppm-v. |
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:I think another editor has now fixed the problem. Thanks for pointing it out. Not everything needs a debate, as Zefr rightly points out. [[User:Qflib|Qflib, aka KeeYou Flib]] ([[User talk:Qflib|talk]]) 14:09, 6 September 2023 (UTC) |
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:Thank you Qlib and Zefr for resolving my {{tl|clarify}} tags. [[User:Bernardirfan|Bernardirfan]] ([[User talk:Bernardirfan|talk]]) 09:41, 16 October 2023 (UTC) |
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https://www.lenntech.com/calculators/ppm/converter-parts-per-million.htm |
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== Semi-protected edit request on 31 August 2023 == |
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== 75 % CO2 only kills insects and small animals? == |
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{{edit semi-protected|Carbon dioxide|answered=yes}} |
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''"At the Bossoleto hot spring near Rapolano Terme in Tuscany, Italy, situated in a bowl-shaped depression about 100 m (330 ft) in diameter, concentrations of CO2 rise to above 75% overnight, sufficient to kill insects and small animals."'' Is there a decimal point missing or something? Given the other values in the article, like: 7 to 10 % CO2 causing suffocation in humans, I'd expect 75% to have more impact. [[User:Samorost1|Samorost1]] ([[User talk:Samorost1|talk]]) 08:11, 1 March 2023 (UTC) |
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[[Special:Contributions/2.49.118.238|2.49.118.238]] ([[User talk:2.49.118.238|talk]]) 14:49, 31 August 2023 (UTC) |
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But if he das he Eed yt account then I don’t see why not just follow the link to the tweet he is posting and |
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:[[File:Red question icon with gradient background.svg|20px|link=|alt=]] '''Not done:''' it's not clear what changes you want to be made. Please mention the specific changes in a [[WP:EDITXY|"change X to Y" format]] and provide a [[Wikipedia:Reliable sources|reliable source]] if appropriate.<!-- Template:ESp --> '''<span style="color:#f535aa">—</span> [[User:Paper9oll|<span style="background:#f535aa;color:#fff;padding:2px;border-radius:5px">Paper9oll</span>]] <span style="color:#f535aa">([[User talk:Paper9oll|🔔]] • [[Special:Contributions/Paper9oll|📝]])</span>''' 14:55, 31 August 2023 (UTC) |
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== Medical uses == |
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== Pop Rocks Section, PSI mismatch. == |
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I removed the following content that is unsourced. All biomedical claims need [[WP:MEDRS]] sourcing because we don't want people to harm themselves. [[User:Clayoquot|Clayoquot]] ([[User_talk:Clayoquot|talk]] <nowiki>|</nowiki> [[Special:Contributions/Clayoquot|contribs]]) 00:46, 30 October 2024 (UTC) |
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Under <u>Commercial Uses/Foods</u> the second paragraph mentions Pop Rocks and lists the psi at 580 among other pressure measurements. The Wikipedia page for Pop Rocks says 730 psi. The source article for the information used for CO2 is a magazine article (116) and does not mention the psi measurement. The source for Pop Rocks itself (<u>Manufacturing</u>) is the actual patent document (9) describing the process. Respectfully Request to use the Pop Rocks pages psi measurement and more credible source. [[User:Omnius777|Omnius]] ([[User talk:Omnius777|talk]]) 00:04, 10 July 2023 (UTC) |
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== general concentration table == |
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=== Medical and pharmacological uses === |
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In medicine, up to 5% carbon dioxide (130 times atmospheric concentration) is added to oxygen for stimulation of breathing after [[apnea]] and to stabilize the {{chem2|O2}}/{{CO2}} balance in blood. |
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Carbon dioxide can be mixed with up to 50% oxygen, forming an inhalable gas; this is known as [[Carbogen]] and has a variety of medical and research uses. |
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I came to this page trying to figure out an answer to the question "hey, my sensor is saying i have 1500ppm in the office, is that good or bad? what's the impact?" I eventually found the "below 1%" section buried in the article, and even there it's one long paragraph with lots of data. |
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Another medical use are the [[Mofetta|mofette]], dry spas that use carbon dioxide from post-volcanic discharge for therapeutic purposes. |
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I figured I would build a shorter summary of the data in a table. I picked some new sources for the data which might not be the best, but it's all sourced. One source might be a little dubious because it's from a sensor manufacturer which may have incentives to describe co2 levels are more alarming than the research actually says they are, but I figured this was still worthwhile, especially considering Canada (and other countries!) restrictions above 1000 ppm. |
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== Due weight issues regarding commercial use == |
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[[File:CO2 use in 2015 - IEA.png|thumb|Uses of CO2 in 2015]] |
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:The table makes sense to me but at the same time I think you should not put any data into it that’s not well sourced. The sensor manufacturer’s website is not a primary source. [[User:Qflib|Qflib, aka KeeYou Flib]] ([[User talk:Qflib|talk]]) 23:42, 10 August 2023 (UTC) |
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The article currently gives a lot of weight to the use of CO2 in the food and beverage industries and various industrial niches. These are relatively small uses of CO2, which is primarily used in urea production and in the oil and gas industry or not used at all. I plan to update it to give a more balanced overview of commercial use. To replace the last paragraph of the lead, I have drafted the following text (adapted largely from the IEA, CC-BY): |
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: Globally, 230 million tonnes (Mt) of carbon dioxide (CO2) are used every year. The largest consumer is the fertilizer industry, where 130 Mt CO2 is used in [[urea]] manufacturing.<ref name=":0">{{Cite web |date=2019-09-25 |title=Putting CO2 to Use – Analysis |url=https://www.iea.org/reports/putting-co2-to-use |access-date=2024-10-30 |website=IEA |language=en-GB}}</ref>{{Rp|page=3}} The oil and gas industry consumes 70 to 80 Mt CO2 annually for [[enhanced oil recovery]].<ref name=":0" />{{Rp|page=3}} Other commercial applications include food and beverage production, metal fabrication, cooling, fire suppression and stimulating plant growth in greenhouses. <ref name=":0" />{{Rp|page=3}} Some usage of CO2 results in long-term sequestration underground or in products. However, as the the potential for commercial use of CO2 is relatively small, the vast majority of CO2 is a waste product.<ref name=":1132">{{Cite journal |last1=Sekera |first1=June |last2=Lichtenberger |first2=Andreas |date=6 October 2020 |title=Assessing Carbon Capture: Public Policy, Science, and Societal Need: A Review of the Literature on Industrial Carbon Removal |journal=Biophysical Economics and Sustainability |volume=5 |issue=3 |pages=14 |bibcode=2020BpES....5...14S |doi=10.1007/s41247-020-00080-5 |issn= |doi-access=free}}Text was copied from this source, which is available under a [[creativecommons:by/4.0/|Creative Commons Attribution 4.0 International License]]</ref> |
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[[User:Clayoquot|Clayoquot]] ([[User_talk:Clayoquot|talk]] <nowiki>|</nowiki> [[Special:Contributions/Clayoquot|contribs]]) 21:38, 30 October 2024 (UTC) |
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==Content cut from article== |
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I've removed the content below from the "Commercial uses" section as they describe technologies that are still at pre-commercial stages of development (or possibly at extremely early commercial deployment if I've missed a recent update). The older predictions of glory have not gone anywhere. Recent sourcing on these issues: Allam cycle [https://www.sciencedirect.com/science/article/abs/pii/S0196890423009536][https://www.iea.org/reports/the-role-of-ccus-in-low-carbon-power-systems/timely-advances-in-carbon-capture-utilisation-and-storage], enhanced coal bed methane recovery[https://www.sciencedirect.com/science/article/pii/S0016236123003897?via%3Dihub], algal biofuels.[https://www.theguardian.com/environment/2023/mar/17/big-oil-algae-biofuel-funding-cut-exxonmobil)] [[User:Clayoquot|Clayoquot]] ([[User_talk:Clayoquot|talk]] <nowiki>|</nowiki> [[Special:Contributions/Clayoquot|contribs]]) 18:54, 1 November 2024 (UTC) |
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Supercritical {{CO2}} is used as the working fluid in the [[Allam power cycle]] engine. |
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== unclear properties values in brackets == |
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In [[enhanced coal bed methane recovery]], carbon dioxide would be pumped into the coal seam to displace methane, as opposed to current methods which primarily rely on the removal of water (to reduce pressure) to make the coal seam release its trapped methane.<ref>{{cite web|url=http://www.ipe.ethz.ch/laboratories/spl/research/adsorption/project03|title=Enhanced coal bed methane recovery|date=31 August 2006|publisher=ETH Zurich|url-status=dead|archive-url=https://web.archive.org/web/20110706232006/http://www.ipe.ethz.ch/laboratories/spl/research/adsorption/project03|archive-date=6 July 2011}}</ref> |
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==== Bio transformation into fuel ==== |
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{{main|Carbon capture and utilization}} |
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It has been proposed that {{CO2}} from power generation be bubbled into ponds to stimulate growth of [[algae]] that could then be converted into [[biodiesel]] fuel.<ref name="csmon">{{cite news| vauthors = Clayton M |url=http://www.csmonitor.com/2006/0111/p01s03-sten.html|title=Algae – like a breath mint for smokestacks|date=11 January 2006|work=[[The Christian Science Monitor]]|access-date=11 October 2007|archive-date=14 September 2008|archive-url=https://web.archive.org/web/20080914134926/http://www.csmonitor.com/2006/0111/p01s03-sten.html|url-status=live}}</ref> A strain of the [[cyanobacterium]] ''[[Synechococcus elongatus]]'' has been genetically engineered to produce the fuels [[isobutyraldehyde]] and [[isobutanol]] from {{CO2}} using photosynthesis.<ref>{{cite journal | vauthors = Atsumi S, Higashide W, Liao JC | title = Direct photosynthetic recycling of carbon dioxide to isobutyraldehyde | journal = Nature Biotechnology | volume = 27 | issue = 12 | pages = 1177–1180 | date = December 2009 | pmid = 19915552 | doi = 10.1038/nbt.1586 | s2cid = 1492698}}</ref> |
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⚫ | ::5.7292(30) MPa, 56.54(30) atm would translate to 5.7292 ± 0.0030 for MPa and 56.54 ± 0.30 atm but '''those are the same measurement just with different units. So the uncertainty can't be the same''' as 5.7262 MPa (-0.003) are 56.5132 atm and not 56.24 - so i conclude these are not uncertainties. (other 7.3743MPa is 72.77868 atm would work (72.778atm) as here the atm value is given with 3 decimals but even if we use 56.54(3)atm it seem to work but 56.542(30) would be 56.512 not 56.5132 as the certainty wouldn't have ⅒ but ¹/₉.₈₆₉₂₃₃ as a factor - So it is very unlikely that the MPa and atm values were from two different measurements with different uncertainties that accidentally have the same numerical value - while just a typo moved a decimal place. [[Special:Contributions/2A01:C22:CD04:2B00:98A2:90A1:EB26:C385|2A01:C22:CD04:2B00:98A2:90A1:EB26:C385]] ([[User talk:2A01:C22:CD04:2B00:98A2:90A1:EB26:C385|talk]]) 09:04, 25 August 2023 (UTC) |
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Researchers have developed an [[electrocatalytic]] technique using enzymes isolated from bacteria to power the chemical reactions which convert {{CO2}} into fuels.<ref>{{Cite journal | vauthors = Cobb S, Badiani V, Dharani A, Wagner A, Zacarias S, Oliveira AR, Pereira I, Reisner E | display-authors = 6 |date=2022-02-28 |title=Fast {{CO2}} hydration kinetics impair heterogeneous but improve enzymatic {{CO2}} reduction catalysis |journal=Nature Chemistry | volume = 14 | issue = 4 |language=en |pages=417–424 |doi=10.1038/s41557-021-00880-2 | pmid = 35228690 | pmc = 7612589 | bibcode = 2022NatCh..14..417C | s2cid = 247160910 |issn=1755-4349}}</ref><ref>{{cite journal | vauthors = Edwardes Moore E, Cobb SJ, Coito AM, Oliveira AR, Pereira IA, Reisner E | title = Understanding the local chemical environment of bioelectrocatalysis | journal = Proceedings of the National Academy of Sciences of the United States of America | volume = 119 | issue = 4 | pages = e2114097119 | date = January 2022 | pmid = 35058361 | pmc = 8795565 | doi = 10.1073/pnas.2114097119 | doi-access = free | bibcode = 2022PNAS..11914097E}}</ref><ref>{{Cite web |date=2022-03-01 |title=Clean Way To Turn {{CO2}} Into Fuel Inspired by Nature |url=http://www.technologynetworks.com/applied-sciences/news/clean-way-to-turn-co2-into-fuel-inspired-by-nature-359088 |access-date=2022-03-02 |website=Applied Sciences from Technology Networks |language=en}}</ref> |
Latest revision as of 01:31, 2 November 2024
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To-do list for Carbon dioxide:
From ACID nomination:
The Fire Extinguisher Entry is outdated and wrong. CO2 IS toxic at concentrations higher than 5%. Design Concentrations for Room Flooding systems with CO2 are 40%+ so CO2 is not suitable for occupied spaces. CO2 Flooding Systems are not supported for use in occupiable spaces though many countries such as USA and other third world countries still misuse CO2 in Fire Suppression Systems because it is cheap. The NFPA supports the use of CO2 on electrical hazards though it is not supported globally because CO2 can cause over pressurization, thermal shock, electrical component damage and has human health/toxicity issues. The NFPA organisation is not the definitive word/authority on Fire Suppression it is just one of many organisations involved in making standards for Fire Protection. The NFPA is really relevent only to the USA. USA codes and standards are typically only relevent to the USA so should not be referenced as the main global Fire standard on a site like wiki which serves a global audience (unless wiki is only for Americans). Though CO2 was used many years ago to protect enclosed spaces on Ships, this is extremely outdated. CO2 has caused fatalities on ships in Navies and merchant fleets that it is now superceded in this application by using extinguishants that support human life at design concentrations such as HFC-227 or Novec-1230. Unlike other countries, America and other third world countries still allow the use of CO2 in some applications where humans can be present because CO2 is cheap and installations are not monitored/controlled. (~GRANT) — Preceding unsigned comment added by 81.140.155.66 (talk • contribs) 10:19, 2 December 2009 (UTC) |
The contentious topics procedure applies to this page. This page is related to climate change, which has been designated as a contentious topic. Editors who repeatedly or seriously fail to adhere to the purpose of Wikipedia, any expected standards of behaviour, or any normal editorial process may be blocked or restricted by an administrator. Editors are advised to familiarise themselves with the contentious topics procedures before editing this page. |
unclear properties values in brackets
[edit]Some values have (15) or (30) added - that needs explaining or correction eg. Vapor pressure 5.7292(30) MPa, 56.54(30) or Critical point (T, P) 304.128(15) K (30.978(15) °C), 7.3773(30) MPa (72.808(30) atm) 2A01:C22:CD7C:E00:7983:CA1C:9736:D1BC (talk) 08:44, 24 August 2023 (UTC)
- It’s not unclear. This is a widely used notation to indicate how much uncertainty is expected in a measured quantity. See the Wikipedia article on uncertainty for more information. Qflib, aka KeeYou Flib (talk) 14:28, 24 August 2023 (UTC)
- Hm, I guess the repeating numbers 15 and 30 does bear closer examination. Maybe they are old citations? Qflib, aka KeeYou Flib (talk) 15:37, 24 August 2023 (UTC)
- First it would be easier to understand if ± was used however if these were uncertainties then
- 5.7292(30) MPa, 56.54(30) atm would translate to 5.7292 ± 0.0030 for MPa and 56.54 ± 0.30 atm but those are the same measurement just with different units. So the uncertainty can't be the same as 5.7262 MPa (-0.003) are 56.5132 atm and not 56.24 - so i conclude these are not uncertainties. (other 7.3743MPa is 72.77868 atm would work (72.778atm) as here the atm value is given with 3 decimals but even if we use 56.54(3)atm it seem to work but 56.542(30) would be 56.512 not 56.5132 as the certainty wouldn't have ⅒ but ¹/₉.₈₆₉₂₃₃ as a factor - So it is very unlikely that the MPa and atm values were from two different measurements with different uncertainties that accidentally have the same numerical value - while just a typo moved a decimal place. 2A01:C22:CD04:2B00:98A2:90A1:EB26:C385 (talk) 09:04, 25 August 2023 (UTC)
- I completely agree. I think that we should therefore remove the numbers within the parentheses, and then try to find better sources. Qflib, aka KeeYou Flib (talk) 22:01, 25 August 2023 (UTC)
Ambiguous units of measurement like "ppm" and "%" across this article
[edit]There are many data with ambiguous units of measurement like "ppm" and "%" across this article (and many other articles across Wikipedia), without a clear explanation what those units stand for. Without a clear explanation, those units can stand for mass per volume, volume per volume, mole per mole or who knows what else. Can someone clarify what those units stand for, despite that is not clarified in the sources? The data about the concentrations of carbon dioxide (and other suffocating and toxic gases and substances) in the air, water, food, drinks, products, etcetera, is a very important information for readers, especially non-expert ones, so, editors should be notified about the very existence of the ambiguous "ppm", "%" and similar ambiguous units across Wikipedia. Let's discuss. I am opening a debate. What do you think? Do you agree or disagree with me, and explain why. Thanks in advance for your opinion. Bernardirfan (talk) 18:08, 30 August 2023 (UTC)
- WP:JUSTFIXIT with a WP:SCIRS source. Zefr (talk) 19:06, 30 August 2023 (UTC)
- I think another editor has now fixed the problem. Thanks for pointing it out. Not everything needs a debate, as Zefr rightly points out. Qflib, aka KeeYou Flib (talk) 14:09, 6 September 2023 (UTC)
- Thank you Qlib and Zefr for resolving my {{clarify}} tags. Bernardirfan (talk) 09:41, 16 October 2023 (UTC)
Semi-protected edit request on 31 August 2023
[edit]This edit request has been answered. Set the |answered= or |ans= parameter to no to reactivate your request. |
2.49.118.238 (talk) 14:49, 31 August 2023 (UTC)
But if he das he Eed yt account then I don’t see why not just follow the link to the tweet he is posting and
- Not done: it's not clear what changes you want to be made. Please mention the specific changes in a "change X to Y" format and provide a reliable source if appropriate. — Paper9oll (🔔 • 📝) 14:55, 31 August 2023 (UTC)
Medical uses
[edit]I removed the following content that is unsourced. All biomedical claims need WP:MEDRS sourcing because we don't want people to harm themselves. Clayoquot (talk | contribs) 00:46, 30 October 2024 (UTC)
Medical and pharmacological uses
[edit]In medicine, up to 5% carbon dioxide (130 times atmospheric concentration) is added to oxygen for stimulation of breathing after apnea and to stabilize the O2/CO2 balance in blood.
Carbon dioxide can be mixed with up to 50% oxygen, forming an inhalable gas; this is known as Carbogen and has a variety of medical and research uses.
Another medical use are the mofette, dry spas that use carbon dioxide from post-volcanic discharge for therapeutic purposes.
Due weight issues regarding commercial use
[edit]The article currently gives a lot of weight to the use of CO2 in the food and beverage industries and various industrial niches. These are relatively small uses of CO2, which is primarily used in urea production and in the oil and gas industry or not used at all. I plan to update it to give a more balanced overview of commercial use. To replace the last paragraph of the lead, I have drafted the following text (adapted largely from the IEA, CC-BY):
- Globally, 230 million tonnes (Mt) of carbon dioxide (CO2) are used every year. The largest consumer is the fertilizer industry, where 130 Mt CO2 is used in urea manufacturing.[1]: 3 The oil and gas industry consumes 70 to 80 Mt CO2 annually for enhanced oil recovery.[1]: 3 Other commercial applications include food and beverage production, metal fabrication, cooling, fire suppression and stimulating plant growth in greenhouses. [1]: 3 Some usage of CO2 results in long-term sequestration underground or in products. However, as the the potential for commercial use of CO2 is relatively small, the vast majority of CO2 is a waste product.[2]
Clayoquot (talk | contribs) 21:38, 30 October 2024 (UTC)
Content cut from article
[edit]I've removed the content below from the "Commercial uses" section as they describe technologies that are still at pre-commercial stages of development (or possibly at extremely early commercial deployment if I've missed a recent update). The older predictions of glory have not gone anywhere. Recent sourcing on these issues: Allam cycle [1][2], enhanced coal bed methane recovery[3], algal biofuels.[4] Clayoquot (talk | contribs) 18:54, 1 November 2024 (UTC)
Supercritical CO2 is used as the working fluid in the Allam power cycle engine.
In enhanced coal bed methane recovery, carbon dioxide would be pumped into the coal seam to displace methane, as opposed to current methods which primarily rely on the removal of water (to reduce pressure) to make the coal seam release its trapped methane.[3]
Bio transformation into fuel
[edit]It has been proposed that CO2 from power generation be bubbled into ponds to stimulate growth of algae that could then be converted into biodiesel fuel.[4] A strain of the cyanobacterium Synechococcus elongatus has been genetically engineered to produce the fuels isobutyraldehyde and isobutanol from CO2 using photosynthesis.[5]
Researchers have developed an electrocatalytic technique using enzymes isolated from bacteria to power the chemical reactions which convert CO2 into fuels.[6][7][8]
- ^ a b c "Putting CO2 to Use – Analysis". IEA. 2019-09-25. Retrieved 2024-10-30.
- ^ Sekera, June; Lichtenberger, Andreas (6 October 2020). "Assessing Carbon Capture: Public Policy, Science, and Societal Need: A Review of the Literature on Industrial Carbon Removal". Biophysical Economics and Sustainability. 5 (3): 14. Bibcode:2020BpES....5...14S. doi:10.1007/s41247-020-00080-5.Text was copied from this source, which is available under a Creative Commons Attribution 4.0 International License
- ^ "Enhanced coal bed methane recovery". ETH Zurich. 31 August 2006. Archived from the original on 6 July 2011.
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