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filingDate 2005-02-18^^<http://www.w3.org/2001/XMLSchema#date>
inventor http://rdf.ncbi.nlm.nih.gov/pubchem/patentinventor/MD5_82d161f0c55a53e578e716cf9dcd1430
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publicationDate 2006-03-15^^<http://www.w3.org/2001/XMLSchema#date>
publicationNumber AR-047964-A1
titleOfInvention DERIVATIVES OF DIFLUOROALQUENO INSECTICIDES AND NEMATICIDES, PESTICIDED COMPOSITIONS THAT CONTAIN THEM AND METHODS FOR PEST CONTROL THAT INVOLVE THEM.
abstract This refers to insecticide and nematicide difluoroalkene derivatives. Methods for controlling a pest of invertebrates are also described which comprise contacting the pest of invertebrates or their environment with a biologically effective amount of a compound of the formula (1), an N-oxide itself or a suitable salt compound ( for example, as a composition described herein: Composition for controlling an invertebrate pest comprising a biologically effective amount of a compound of the formula (1), an N-oxide thereof or a suitable salt of the compound and at least an additional component selected from the group consisting of a surfactant, a solid diluent, a liquid diluent and optionally a biologically active compound or additional agent: Spray composition containing the compound of formula (1) and a propellant; and a composition of bait containing said compound, one or more feed materials and optionally an attractor and a humectant Claim 1: A compound of the formula (1), an N-oxide thereof or an agronomic or non-agronomically suitable salt thereof, wherein Q is Q-1 or Q-2; Y is H, F, Cl, or CH3; A is CN, C1-6 alkyl, OR1a, SR1a, NR1aR2a or CONR1bR2b; Z is O, S or NR3; W is N or CR4; J1 and J2 are C1-6 alkyl, C2-6 alkenyl, C3-6 alkynyl, C3-7 cycloalkyl, C4-8 cycloalkylalkyl, C1-4 alkoxy, C2-6 alkoxycarbonyl or C2- alkylcarbonyl 6 or C2-6 alkylcarbonyl, each optionally substituted with a G and each optionally substituted with one or more R5, or J1 and J2 are G, NO2, CN, OH, NR6R7, CONR6R7, OCONR6R7, C1-4 alkyl sulfonyl, C (O) G or S (O) 2G; each G is independently a phenyl ring, a naphthyl ring system, a 5- or 6-membered heteroaromatic ring or a fused 8-, 9-, or 10-membered heterocyclic ring system, each ring or ring system optionally substituted with 1 at 5 R8; R1a and R1b are H, G, CN, or C1-6 alkyl, C2-6 alkenyl, C3-6 alkynyl; C3-7 cycloalkyl or C4-8 cycloalkylalkyl, each optionally substituted with one or more substituents selected from the group consisting of G, halogen, CN, NO2, C1-4 alkoxy, C1-4 alkylthio, C1 alkylsulfinyl -4, C1-4 alkylsulfonyl, C2-4 alkoxycarbonyl, C1-4 alkylamino, C2-8 dialkylamino and C3-6 cycloalkylamino; R2a and R2b are H, or C1-6 alkyl, C2-6 alkenyl, C3-6 alkynyl, C3-7 cycloalkyl or C4-8 cycloalkylalkyl, each optionally substituted with one or more substituents selected from the group which It consists of halogen, CN, NO2, C1-4 alkoxy, C1-4 alkylthio, C1-4 alkylsulfinyl, C1-4 alkylsulfonyl, C2-4 alkoxycarbonyl, C1-4 alkylamino, C2-8 dialkylamino and C3-6 cycloalkylamino, or R1a and R2a or R1b and R2b are taken together with the N to which they are attached to form a ring that includes 2 to 5 C atoms and optionally an additional N, S or O atom, the ring it is optionally substituted with 1 to 2 R5; R3 is H, C1-6 alkyl, C2-6 alkenyl, C3-6 alkynyl, C3-7 cycloalkyl or C4-8 cycloalkylalkyl R4 is H, C1-4 alkyl or CN; or R4 is a phenyl ring optionally substituted with 1 to 5 R8; each R5 is independently halogen, CN, NO2, C 1-6 alkyl, C 2-6 alkenyl, C 2-6 alkynyl, C 3-6 cycloalkyl, C 1-6 haloalkyl, C 2-6 haloalkenyl, C 2- haloalkynyl 6, C3-6 halocycloalkyl, C1-4 alkoxy, C1-4 haloalkyl, C1-4 haloalkoxy, C1-4 alkylthio, C1-4 alkylsulfinyl, C1-4 alkylsulfonyl, C1-4 haloalkylsulfinyl, haloalkylsulfonyl C1-4, C1-4 alkylamino, C2-8 dialkylamino, C3-8 cycloalkylamino, C2-6 alkylcarbonyl, or C2-6 alkoxycarbonyl; R6 and R7 are each independently H, or C1-6 alkyl, C3-6 alkenyl, C3-6 alkynyl, C3-6 cycloalkyl, C2-6 alkylcarbonyl or C2-6 alkoxycarbonyl, each optionally substituted with halogen, or R6 and R7 can be taken together with the N to which they are attached to form a ring that includes 2 to 5 C atoms and optionally an additional atom of N, S or O, the ring is optionally substituted with halogen; each R8 is independently halogen, CN, NO2, C1-6 alkyl, C2-6 alkenyl, C2-6 alkynyl, C3-6 cycloalkyl, C1-6 haloalkyl, C2-6 haloalkenyl, C2- haloalkynyl 6, C3-6 halocycloalkyl, C1-4 alkoxy, C1-4 haloalkoxy, C1-4 alkylthio, C1-4 alkylsulfinyl, C1-4 alkylsulfonyl, C1-4 haloalkyl, C1-4 haloalkyl, C1-4 haloalkylsulfonyl, C1-4 alkylamino, C2-8 dialkylamino, C3-6 cycloalkylamino, C2-6 alkylcarbonyl or C2-6 alkoxycarbonyl, or each R8 is independently a phenoxy ring or a phenyl ring, each ring optionally substituted with 1 to 5 R5; R 10 is H, or C 1-6 alkyl, C 2-6 alkenyl, C 2-6 alkynyl, C 3-7 cycloalkyl or C 4-8 cycloalkylalkyl, each optionally substituted with one or more substituents selected from the group consisting of halogen, CN, NO2, C1-4 alkoxy, C1-4 alkylthio, C1-4 alkylsulfinyl, C1-4 alkylsulfonyl, C2-4 alkoxycarbonyl, C1-4 alkylamino, C2-8 dialkylamino and cycloalkylamino C3-6; or R10 is C1-6 alkylthio, CN, CO2R12, CONR12R13 or phenyl optionally substituted with 1 to 5 R11; each R11 is independently halogen, CN, NO2, C1-6 alkyl, C2-6 alkenyl, C2-6 alkynyl, C3-6 cycloalkyl, C1-6 haloalkyl, C2-6 haloalkenyl, C2- haloalkynyl 6, halocycloalkyl e C3-6, alkoxy of C1-4, haloalkoxy of C1-4, alkylthio of C1-4, alkylsulfinyl of C1-4, alkylsulfonyl of C1-4, haloalkylthio of C1-4, haloalkylsulfinyl of C1-4, C 1-4 haloalkylsulfonyl, C 1-4 alkylamino, C 2-8 dialkylamino, C 3-6 cycloalkylamino, C 2-6 alkylcarbonyl, or C 2-6 alkoxycarbonyl; R12 and R13 are each independently H or C1-6 alkyl; and n is 1, 3 or 5; as long as (1) when Y is F, Z is S, n is 1, A is SR1a, NR1aR2a and W is N, then J1 is not alkyl, G, CN or cycloalkyl; (2) J1 is not 3- (4- trifluoromethyl) pyridinylcarbonyl or an N-oxide thereof; (3) when R10 is H, methyl, ethyl, phenyl or 4-fluorophenyl and J2 is phenyl substituted with R8, then R8 is not 2-fluoroethoxy; (4) when Z is NH, W is N and AQ is SR1a, then J1 is not phenyl substituted at positions 2 and 6 with alkyl or cycloalkyl; and (5) when Z is NR3, W is N or CH, A is NR1aR2a and R1a or R2a is H or alkyl, then J1 is not CN or NO2.
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