http://rdf.ncbi.nlm.nih.gov/pubchem/patent/CA-2028877-C
Outgoing Links
| Predicate | Object |
|---|---|
| assignee | http://rdf.ncbi.nlm.nih.gov/pubchem/patentassignee/MD5_b9ff2988b0c12145a439b1a8945d0e6d |
| classificationCPCInventive | http://rdf.ncbi.nlm.nih.gov/pubchem/patentcpc/C08F4-00 http://rdf.ncbi.nlm.nih.gov/pubchem/patentcpc/C08F210-06 |
| classificationIPCInventive | http://rdf.ncbi.nlm.nih.gov/pubchem/patentipc/C08F210-06 http://rdf.ncbi.nlm.nih.gov/pubchem/patentipc/C08F2-34 http://rdf.ncbi.nlm.nih.gov/pubchem/patentipc/C08F10-00 http://rdf.ncbi.nlm.nih.gov/pubchem/patentipc/C08F4-60 http://rdf.ncbi.nlm.nih.gov/pubchem/patentipc/C08F4-658 http://rdf.ncbi.nlm.nih.gov/pubchem/patentipc/C08F210-14 |
| filingDate | 1990-10-30^^<http://www.w3.org/2001/XMLSchema#date> |
| grantDate | 1996-12-24^^<http://www.w3.org/2001/XMLSchema#date> |
| inventor | http://rdf.ncbi.nlm.nih.gov/pubchem/patentinventor/MD5_cc7eec151a477ed98170d197f41a3192 http://rdf.ncbi.nlm.nih.gov/pubchem/patentinventor/MD5_c3e11d7aa1f04ec466fccc226a8cdbcd http://rdf.ncbi.nlm.nih.gov/pubchem/patentinventor/MD5_b8e83307230dd33034867684c8be260f |
| publicationDate | 1996-12-24^^<http://www.w3.org/2001/XMLSchema#date> |
| publicationNumber | CA-2028877-C |
| titleOfInvention | Process for the preparation of random copolymers |
| abstract | A process for the copolymerization of a mixture of monomers comprising propylene and 1-hexene which comprises contacting the monomers and, optionally, hydrogen in the gas phase in a single stage reaction zone, under polymerization conditions, with a catalyst system comprising (i) a solid catalyst precursor, which includes magnesium; titanium; a halogen which is chlorine, bromine, or iodine, or a mixture thereof; and a polycarboxylic acid ester containing two coplanar ester groups attached to adjacent carbon atoms; (ii) a hydrocarbyl aluminum cocatalyst; and (iii) a silicon compound containing at least one silicon-oxygen-carbon group, at a temperature of from about 50°C to about 90°C, wherein: (a) the atomic ratio of aluminum to titanium is in the range of about 10 to about 300; (b) the molar ratio of aluminum to silicon compound is in the range of about 0.5 to about 10; (c) the propylene partial pressure is in the range of about 50 to about 400 psi; (d) the 1-hexene partial pressure is in the range of about 1 to about 15 psi; (e) if hydrogen is present, the hydrogen partial pressure is in the range of up to about 80 psi; (f) the superficial gas velocity is in the range of about 1 to about 3 feet per second; and (g) the molar ratio of 1-hexene to propylene is in the range of about 0.01:1 to about 0.08:1. |
| priorityDate | 1989-10-31^^<http://www.w3.org/2001/XMLSchema#date> |
| type | http://data.epo.org/linked-data/def/patent/Publication |
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