http://rdf.ncbi.nlm.nih.gov/pubchem/patent/CN-109687018-A

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filingDate 2018-12-25^^<http://www.w3.org/2001/XMLSchema#date>
inventor http://rdf.ncbi.nlm.nih.gov/pubchem/patentinventor/MD5_c0ebbcd050c93af842304eaffa94eb68
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publicationDate 2019-04-26^^<http://www.w3.org/2001/XMLSchema#date>
publicationNumber CN-109687018-A
titleOfInvention A kind of layered anti-calcium ore structure sodium ion solid electrolyte and preparation method thereof
abstract The invention relates to a layered anti-calcite structure sodium ion solid electrolyte and a preparation method thereof. The sodium ion solid electrolyte has the following structural formula: Na 4-2d-c Li c R d A 1+ e X 2-2e , wherein 0≤c≤1; R is among Ca 2+ and Ba 2+ One or both of the elements, 0≤d≤0.5; A is one or both of O and S elements, 0≤e≤0.1; X is one or both of the halogens. The sodium ion solid electrolyte provided by the present invention is based on a layered (dual-type) anti-perovskite structure, and has good thermodynamic stability. When sodium ions are transported, the sodium vacancies along the octahedral apex of the structure and/or Or doping vacancies for diffusion is beneficial to achieve lower diffusion activation energy, thereby improving the room temperature conductivity of sodium ions and realizing two-dimensional ultrafast ion transport.
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priorityDate 2018-12-25^^<http://www.w3.org/2001/XMLSchema#date>
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