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publicationDate 1981-07-15^^<http://www.w3.org/2001/XMLSchema#date>
publicationNumber EP-0032050-A2
titleOfInvention Polysiloxane Elastomer composition and dispensable precursor therefor
abstract A dispensable precursor composition for highly filled, thermally conductive elastomers that is adapted to fill deep section mold cavities, which composition is an intimate admixture of a first component comprising an olefinically unsaturated crosslinkable polysiloxane and a second component comprising a silyl hydride functional siloxane which composition comprises:n I. 100 parts by weight of the crosslinkable polysiloxane which has a formula:n wherein at least most of the Ra's and Rb's are selected from (A) saturated hydrocarbyl or hydrocarbyloxy groups having a total of 1 to about 10 carbon atoms that are alkyl or aryl or alkyl and aryl and (B) allyl or vinyl groups but wherein up to about 25% of the Rb's may ben wherein at least most of the Rc's and Rd's are selected from (A) and (B) above but up to about 10%ofthe Rd's may contain additional siloxane units with substituents selected from (A) and (B) or still additional siloxane units; and still further wherein (1) the average number of m plus n per polymer molecule is between about 100 and 300 and (2) there is an average total of above about 1.5 but lower than 6 crosslinking sites selected from the vinyl, allyl or vinyl and allyl groups per polymer molecule; II. about 60-500 parts by weight of finely divided particulate comprising:n (A) silica particulate at a weight ratio to the polysiloxane of 1. of between about 0.3 to 2.5:1 wherein the silica particulate comprises:n 1. ground silica having an average particle diameter between about 0.1 and 15 microns; and 2. fumed silica having an average particle diameter between about 0.005 and 0.015 microns; (B) thermally conductive powder at a weight ratio to the polysiloxane of I. of between about 0.3 to 2.5:1; III. a viscosity modifier comprising a silicone oil having a viscosity between about 1000-1,000,000 centistokes at 25°C at a weight ratio to the particulate of II of between about 1:20-1:4 oil to particulate;
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priorityDate 1980-01-04^^<http://www.w3.org/2001/XMLSchema#date>
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