http://rdf.ncbi.nlm.nih.gov/pubchem/patent/EP-0149832-A2

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filingDate 1984-12-20^^<http://www.w3.org/2001/XMLSchema#date>
inventor http://rdf.ncbi.nlm.nih.gov/pubchem/patentinventor/MD5_80747c825613a4806d901c67e4e5343e
http://rdf.ncbi.nlm.nih.gov/pubchem/patentinventor/MD5_2e5ca444dbef50bfb007eb9ba45ace00
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publicationDate 1985-07-31^^<http://www.w3.org/2001/XMLSchema#date>
publicationNumber EP-0149832-A2
titleOfInvention Preparation of thiolcarbamates
abstract R 3 und R 4 unabhängig voneinander für Wasserstoff oder eine Alkylgruppe mit 1-4 Kohlenstoffatomen stehen und letztere durch Halogen oder eine Sauerstoff. Schwefel und/oder Stickstoff enthaltende Gruppe substituiert sein kann, und R 5 und R 6 beide für Wasserstoff stehen oder gemeinsam eine chemische Bindung bilden. The invention relates to a new process for the produc- tion of the known thiolcarbamic acid esters of R 1 and R 2 general formula (I) independently of one another for hydrogen or a straight or branched alkyl group with 1-6 carbon atoms or alkanyl group with 2-6 carbon atoms or for alkyl group with 1-6 or alkenyl group with 2-6 which is mono- or polysubstituted by halogen, oxygen, sulfur and / or nitrogen Are carbon atoms or together form an optionally substituted α, ω -alkylene group with 4-6 carbon atoms, R 3 and R 4 independently represent hydrogen or an alkyl group with 1-4 carbon atoms and the latter by halogen or an oxygen. Group containing sulfur and / or nitrogen may be substituted, and R 5 and R 6 both represent hydrogen or together form a chemical bond. n n n a) Thiocarbamatsalze der allgemeinen Formel (II)n worin Y für ein primäres, sekundäres oder tertiäres Ammoniumion oder ein Alkalimetallion bedeutet, oder b) Amine der allgemeinen Formel (III)n zusammen mit Kohlenmonoxyd und Schwefel, oder c) Amine der allgemeinen Formel (III) zusammen mit Carbonylsulfid nmit Alkinen der allgemeinen Formel (IV)n umsetzt und gewünschtenfalls die erhaltene ungesättigte Verbindung der allgemeinen Formel (I) unter Aufspaltung der Doppelbindung hydriert. The compounds of general formula (I) are prepared by a) thiocarbamate salts of the general formula (II) wherein Y represents a primary, secondary or tertiary ammonium ion or an alkali metal ion, or b) amines of the general formula (III) together with carbon monoxide and sulfur, or c) amines of the general formula (III) together with carbonyl sulfide with alkynes of the general formula (IV) reacted and, if desired, the unsaturated compound of the general formula (I) obtained is hydrogenated with the double bond split.
isCitedBy http://rdf.ncbi.nlm.nih.gov/pubchem/patent/US-9783712-B2
priorityDate 1983-12-29^^<http://www.w3.org/2001/XMLSchema#date>
type http://data.epo.org/linked-data/def/patent/Publication

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