http://rdf.ncbi.nlm.nih.gov/pubchem/patent/EP-0190518-A1
Outgoing Links
| Predicate | Object |
|---|---|
| assignee | http://rdf.ncbi.nlm.nih.gov/pubchem/patentassignee/MD5_1c214da6949fa3003839046b4e7fa92b |
| classificationCPCAdditional | http://rdf.ncbi.nlm.nih.gov/pubchem/patentcpc/B01J2531-16 http://rdf.ncbi.nlm.nih.gov/pubchem/patentcpc/C07C2531-16 http://rdf.ncbi.nlm.nih.gov/pubchem/patentcpc/C07C2531-14 http://rdf.ncbi.nlm.nih.gov/pubchem/patentcpc/C07C2531-06 http://rdf.ncbi.nlm.nih.gov/pubchem/patentcpc/Y02P20-52 http://rdf.ncbi.nlm.nih.gov/pubchem/patentcpc/C07C2531-12 http://rdf.ncbi.nlm.nih.gov/pubchem/patentcpc/B01J2531-62 |
| classificationCPCInventive | http://rdf.ncbi.nlm.nih.gov/pubchem/patentcpc/B01J31-26 http://rdf.ncbi.nlm.nih.gov/pubchem/patentcpc/B01J31-2234 http://rdf.ncbi.nlm.nih.gov/pubchem/patentcpc/B01J31-2291 http://rdf.ncbi.nlm.nih.gov/pubchem/patentcpc/B01J31-122 http://rdf.ncbi.nlm.nih.gov/pubchem/patentcpc/C07C29-154 http://rdf.ncbi.nlm.nih.gov/pubchem/patentcpc/C07C1-063 |
| classificationIPCAdditional | http://rdf.ncbi.nlm.nih.gov/pubchem/patentipc/C07C31-02 |
| classificationIPCInventive | http://rdf.ncbi.nlm.nih.gov/pubchem/patentipc/C07C1-06 http://rdf.ncbi.nlm.nih.gov/pubchem/patentipc/C07C27-06 http://rdf.ncbi.nlm.nih.gov/pubchem/patentipc/B01J31-22 http://rdf.ncbi.nlm.nih.gov/pubchem/patentipc/B01J31-26 http://rdf.ncbi.nlm.nih.gov/pubchem/patentipc/B01J31-16 http://rdf.ncbi.nlm.nih.gov/pubchem/patentipc/C07C9-02 http://rdf.ncbi.nlm.nih.gov/pubchem/patentipc/C07C29-15 http://rdf.ncbi.nlm.nih.gov/pubchem/patentipc/C07C29-154 |
| filingDate | 1985-12-02^^<http://www.w3.org/2001/XMLSchema#date> |
| inventor | http://rdf.ncbi.nlm.nih.gov/pubchem/patentinventor/MD5_a50e7b7ec58cbc40e0651fa3b5c47f70 http://rdf.ncbi.nlm.nih.gov/pubchem/patentinventor/MD5_4b58f1ff5c3f7233d676204844485775 |
| publicationDate | 1986-08-13^^<http://www.w3.org/2001/XMLSchema#date> |
| publicationNumber | EP-0190518-A1 |
| titleOfInvention | Carbon monoxide hydrocondensation catalyst |
| abstract | (a) au moins un complexe de formule CuL n dans laquelle n est le nombre de ligands complexant le cuivre et L est un ligand ionique ou covalent, (b) au moins un activateur de formule M'R m dans laquelle M' est un métal choisi parmi aluminium, lithium, sodium, magnésium et zinc, m est la valence du métal M' et R est choisi parmi l'atome d'hydrogène et les radicaux hydrocarbonés, le rapport molaire (b)/(a) étant compris entre 0,3 et 20, et (c) au moins un composé choisi parmi les diènes conjugués, les phosphmes, les amines, les arsines et les phosphites. le rapport molaire (c) (a) étant compns entre 1 et 20 Sa préparation est effectuée par mise en contact des composants (a). (b) et (c) dans au moins un solvant aromatique essentiellement anhydre et au moins partiellement sous atmosphère de gaz inerte Le catalyseur est applicable à la fabncanon d'hydrocarbures et de composés oxygénés aliphatiques par réaction entre le monoxyde de carbone et 1 hydrugene dans un rapport molair CO H 2 compris entre 0.1 et 2 sous une pression comprise entre 5 et 400 bars. à une temperature comprise entre 210° et 400°C. le temps de séjour du mélange éactionnel étant compris entre 0,1 et 120 secondes et la éaction étant effectuée en présence d'au moins un solvant. The catalyst according to the invention comprises at least one product obtained by bringing together: (a) at least one complex of formula CuL n in which n is the number of ligands complexing copper and L is an ionic or covalent ligand, (b) at least one activator of formula M'R m in which M 'is a metal chosen from aluminum, lithium, sodium, magnesium and zinc, m is the valence of the metal M' and R is chosen from the atom of hydrogen and hydrocarbon radicals, the molar ratio (b) / (a) being between 0.3 and 20, and (c) at least one compound chosen from conjugated dienes, phosphmes, amines, arsines and phosphites. the molar ratio (c) (a) being between 1 and 20 Its preparation is carried out by bringing the components (a) into contact. (b) and (c) in at least one essentially anhydrous aromatic solvent and at least partially under an inert gas atmosphere The catalyst is applicable to the manufacture of hydrocarbons and oxygenated aliphatic compounds by reaction between carbon monoxide and 1 hydrugene in a molar ratio CO H 2 of between 0.1 and 2 under a pressure of between 5 and 400 bars. at a temperature between 210 ° and 400 ° C. the residence time of the reaction mixture being between 0.1 and 120 seconds and the reaction being carried out in the presence of at least one solvent. |
| priorityDate | 1984-12-05^^<http://www.w3.org/2001/XMLSchema#date> |
| type | http://data.epo.org/linked-data/def/patent/Publication |
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