http://rdf.ncbi.nlm.nih.gov/pubchem/patent/EP-0252837-B1

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filingDate 1987-07-07^^<http://www.w3.org/2001/XMLSchema#date>
grantDate 1992-11-11^^<http://www.w3.org/2001/XMLSchema#date>
publicationDate 1992-11-11^^<http://www.w3.org/2001/XMLSchema#date>
publicationNumber EP-0252837-B1
titleOfInvention Process for the preparation of dianhydrides of fructofuranose and their use as nutritive additives
abstract The process consists in reacting a carbohydrate containing at least one fructofuranose unit in which the hydroxyls at C-3, C-4 and C-6 are substituted by a protecting group which is stable in hydrogen fluoride, usually an ester group, with hydrogen fluoride (HF) which is generally diluted in a solvent which is inert or relatively nonreactive towards HF, and extracting the reaction product with dichloromethane. The predominant component hexa-O-acetyl- alpha -D-fructofuranose- beta -D-fructofuranose 1,2':2,1'-dianhydride can be separated at this stage from its isomer, hexa-O-acetyl- beta , beta -difructofuranose dianhydride. Deacetylation of the predominant component, or of the entire mixture of carbohydrates resulting from the reaction, results in compounds exhibiting a pleasant sweet taste, which can be employed in foodstuffs as noncariogenic sweeteners of low calorific value.
priorityDate 1986-07-11^^<http://www.w3.org/2001/XMLSchema#date>
type http://data.epo.org/linked-data/def/patent/Publication

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