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filingDate 1988-12-23^^<http://www.w3.org/2001/XMLSchema#date>
inventor http://rdf.ncbi.nlm.nih.gov/pubchem/patentinventor/MD5_ed9eb0bfff70c098606e14d675a738e4
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publicationDate 1989-07-05^^<http://www.w3.org/2001/XMLSchema#date>
publicationNumber EP-0322811-A2
titleOfInvention Process for producing aldehydes or mixtures of ketones and aldehydes
abstract A hydrocarbonylation process for producing an aldehyde or a mixture of a ketone and an aldehyde which comprises:n (I) forming a reaction mixture comprising:n (a) a catalytic amount of a complex catalyst consisting essentially of rhodium in complex combination with:n (i) a triorganophosphine, and (ii) a carboxylic acid having a phenyl group substituted at the para position with a non-reactive electron-withdrawing group, said phenyl group being free of further substitution amd said electron withdrawing group being substantially non-reactive in said process; (b) an alpha-olefin having 2 to 5 carbon atoms, (c) carbon monixide, and (d) hydrogen with the proviso that the reaction mixture has mole ratio of said carboxylic acid to rhodium of at least about 2; and (II) maintaining the reaction mixture at a temperature and pressure at which said (b), (c) and (d) react to form an aldehyde or a mixture of an aldehyde and a ketone.
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