http://rdf.ncbi.nlm.nih.gov/pubchem/patent/EP-0551856-A1

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filingDate 1993-01-11^^<http://www.w3.org/2001/XMLSchema#date>
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publicationDate 1993-07-21^^<http://www.w3.org/2001/XMLSchema#date>
publicationNumber EP-0551856-A1
titleOfInvention Probe for a scanning tunneling microscope and method of manufacturing a probe
abstract Disclosed is a probe for use in a scanning tunneling microscope which can measure a macromolecule, i.e., a protein molecule. The probe is manufactured by covering a metal wire having a sharp end with a thin organic film, removing an end of the metal wire by an electric field evaporation process, electrodepositing metal ions on the metal wire and removing a portion of the organic film. A monomolecular film is formed on the surface of a metal wire by chemically adsorbing a chlorosilane based chemical adsorbent. Only a tip of the chemically adsorbed film is removed by the electric field evaporation procedure, and the metal ions are electrodeposited on the tip of the metal wire. As a result, a sharp metal tip is formed. After that, the chemically adsorbed film is removed by alkyl treatment.
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