http://rdf.ncbi.nlm.nih.gov/pubchem/patent/EP-0555858-A2

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filingDate 1993-02-11^^<http://www.w3.org/2001/XMLSchema#date>
inventor http://rdf.ncbi.nlm.nih.gov/pubchem/patentinventor/MD5_abb18267de8d0ec051743e91ff5649ad
publicationDate 1993-08-18^^<http://www.w3.org/2001/XMLSchema#date>
publicationNumber EP-0555858-A2
titleOfInvention Method of dry etching a polycide without using a CFC gas
abstract A dry etching method for performing one-stage anisotropic etching of a W-polycide film without using a CFC (chlorofluorocarbon) gas is disclosed. The W-polycide film on a substrate is etched by using sulfur halide such as S₂Cl₂ and S₂Br₂ for an etching gas while heating the substrate within a temperature range of up to 90°C. Free S released from the sulfur halide is deposited on the substrate within the temperature range, thereby contributing to improvement of selectivity and anisotropy, and Cl* and Br* become etchants. Although WCl x and WBr x , which are etching reaction products, have low vapor pressure at a normal temperature and under normal pressure, WCl x and WBr x may be eliminated sufficiently under reduced pressure and heated conditions. Since F* is not formed in a plasma, no undercut is generated on an underlying polysilicon layer. Also, since C does not exist, particle pollution can be prevented and selectivity for a gate oxide film can be improved. If a nitrogen based compound, such as N₂, is added to the sulfur halide, deposition of sulfur nitride based compounds can be expected, and the wafer heating temperature can be raised up to 130°C.
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priorityDate 1992-02-14^^<http://www.w3.org/2001/XMLSchema#date>
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