| abstract |
A catalyst system useful to polymerize and co-polymerize polar and non-polar olefin monomers is formed by in situ reduction with a reducing agent of a catalyst precursor comprising <?in-line-formulae description="In-line Formulae" end="lead"?>{Cp*MRR'<SUB>n</SUB>}<SUP>+</SUP>{A}<SUP>-</SUP><?in-line-formulae description="In-line Formulae" end="tail"?> wherein Cp* is a cyclopentadienyl or substituted cyclopentadienyl moiety; M is an early transition metal; R is a C<SUB>1</SUB>-C<SUB>20 </SUB>hydrocarbyl; R' are independently selected from hydride, C<SUB>1</SUB>-C<SUB>20 </SUB>hydrocarbyl, SiR''<SUB>3</SUB>, NR''<SUB>2</SUB>, OR'', SR'', GeR''<SUB>3</SUB>, SnR''<SUB>3</SUB>, and C-C-containing groups (R''=C<SUB>1</SUB>-C<SUB>10 </SUB>hydrocarbyl); n is an integer selected to balance the oxidation state of M; and A is a suitable non-coordinating anionic cocatalyst or precursor. This catalyst system may form stereoregular olefin polymers including syndiotactic polymers of styrene and methylmethacrylate and isotactic copolymers of polar and nonpolar olefin monomers such as methylmethacrylate and styrene. |