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filingDate 2017-09-26^^<http://www.w3.org/2001/XMLSchema#date>
inventor http://rdf.ncbi.nlm.nih.gov/pubchem/patentinventor/MD5_4b55cb9b63e1a5fec77805f196c6c861
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publicationDate 2018-03-28^^<http://www.w3.org/2001/XMLSchema#date>
publicationNumber EP-3300155-A1
titleOfInvention Crosslinked wholly aromatic proton conductive polymeric electrolytes based on quinoline units
abstract The current invention presents new polymer electrolytes comprising phenyl-quinoline units. These polymers are prepared through the homopolymerization of A-B difunctional monomers of phenyl-quinoline that bear simultaneously hydroxyl-phenyl and polyfluorinated phenyl rings. Extended studies were performed for the optimization of the polymerization conditions and of the molecular characteristics of the final homopolymers. Further stabilization of the polymeric structures is achieved via cross-linking of the polymeric chains through nucleative aromatic substitution of the remaining fluorine atoms of the structures that bear polyfluorinated rings. As cross-linkers are employed aromatic dihydroxyl substituted compounds either monomers or homo-oligomers or co- oligomers having free end hydroxyl units. Membranes of the above polymers were characterized for their properties such as mechanical, thermal and doping ability in strong protic acids. The membranes were used for the preparation of membrane electrode assemblies (MEAs) and were studied in single fuel cells presenting high ionic conductivities and operational stability at temperatures from 160°C up to 210°C.
priorityDate 2016-09-26^^<http://www.w3.org/2001/XMLSchema#date>
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