http://rdf.ncbi.nlm.nih.gov/pubchem/patent/GB-1035626-A
Outgoing Links
| Predicate | Object |
|---|---|
| assignee | http://rdf.ncbi.nlm.nih.gov/pubchem/patentassignee/MD5_73ee0bacab5a7576a6a3244747f6ea99 |
| classificationCPCAdditional | http://rdf.ncbi.nlm.nih.gov/pubchem/patentcpc/C07C2601-14 |
| classificationCPCInventive | http://rdf.ncbi.nlm.nih.gov/pubchem/patentcpc/C07C29-52 |
| classificationIPCInventive | http://rdf.ncbi.nlm.nih.gov/pubchem/patentipc/C07C29-52 |
| filingDate | 1962-06-28^^<http://www.w3.org/2001/XMLSchema#date> |
| inventor | http://rdf.ncbi.nlm.nih.gov/pubchem/patentinventor/MD5_33f81e9b24701790c6ab164a8cc9d943 |
| publicationDate | 1966-07-13^^<http://www.w3.org/2001/XMLSchema#date> |
| publicationNumber | GB-1035626-A |
| titleOfInvention | Improvements in and relating to the oxidation of hydrocarbons |
| abstract | Oxygenated organic compounds, including alcohols, are obtained by contacting an aliphatic hydrocarbon with an oxygen-containing gas at an elevated temperature in the presence of an ester alcohol corresponding to the hydrocarbon with a boron acid, the ester being added to the hydrocarbon before contacting it with the oxygen-containing gas. The boron acid may be orthoboric acid, metaboric acid, boronic acid, R2BOH, or boronic acid RB(OH)2 in which R is an alkyl group. Suitable starting materials are straight chain or branched paraffins and cycloparaffins, e.g. n-octane and cyclohexane. The process may be carried out in the presence of small amounts of a compound of a transition metal, e.g. cobalt, nickel, manganese, vanadium, rhodium or ruthenium. The process is preferably carried out at a temperature of 100-200 DEG C. The oxygen-containing gas may be air, or air enriched with oxygen or diluted with nitrogen. Preferably, an air/nitrogen mixture containing not more than 10% of oxygen is used. The products are chiefly secondary alcohols and ketones with smaller amounts of primary alcohols and aldehydes. Examples are given of the oxidation of cyclohexane to mainly cyclohexanol and cyclohexanone. |
| priorityDate | 1962-06-28^^<http://www.w3.org/2001/XMLSchema#date> |
| type | http://data.epo.org/linked-data/def/patent/Publication |
Incoming Links
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