| abstract |
A method for producing a coupling compound is provided. Nickel compounds and general formula (i): (Wherein R 3 is alkyl, R 4 is hydrogen, alkyl, 1 is an integer of 1 to 3, and p and q are integers of 0 to 2), in the presence of a catalyst, Formula (1): (R 1 X 1 n ) (1) N ′ mol of the organic halide represented by the formula (2) {R 2 (BX 2 2 ) n ′ } (2) (Wherein, X 1 is bromine, iodine, R 1 is a hydrocarbon group in which the carbon atom within the γ-position from X 1 is an sp 3 carbon atom, and n and n ′ are 1 or 2, R 2 is aryl or alkenyl, X 2 is a hydroxyl group or alkoxyl, m is 1, 2, or m ≦ n. And general formula (3): (Y-) (n -1) R 1 -R 2 - (R 1) (n '-1) (3) (Wherein Y represents R 2 or X 1 ). [Selection figure] None |