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filingDate 1991-11-21^^<http://www.w3.org/2001/XMLSchema#date>
inventor http://rdf.ncbi.nlm.nih.gov/pubchem/patentinventor/MD5_8d1d34da34f8291c3ac2f4fcf465bbd2
http://rdf.ncbi.nlm.nih.gov/pubchem/patentinventor/MD5_b60ab77e3c0e66c9c69645a0c8fa8011
publicationDate 1993-07-09^^<http://www.w3.org/2001/XMLSchema#date>
publicationNumber JP-H05170780-A
titleOfInvention Water-soluble alkali metal sulfonate-substituted binaphthylphosphine transition metal complex and asymmetric hydrogenation method using the same
abstract (57) [Summary] [Purpose] Has high performance as a catalyst for asymmetric synthesis reactions, It is an object of the present invention to develop a novel phosphine complex that can be easily separated from the product and can be reused, and to develop a method for efficiently performing an asymmetric hydrogenation reaction. [Structure] The novel phosphine complex of the present invention has a chemical structure represented by the general formula (1) in the specification, and a particularly novel point is that the binaphthylphosphine in the complex is substituted with an alkali metal sulfonate base. That is the point. Further, the asymmetric hydrogenation method of the present invention is characterized in that the above novel phosphine complex is used as a catalyst. When the novel phosphine complex of the present invention is used as a catalyst, it is easy to separate the reaction product from the catalyst after the asymmetric hydrogenation reaction. Further, the novel phosphine complex of the present invention has an asymmetric hydrogenation. It can be repeatedly used as a catalyst for the chemical reaction.
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http://rdf.ncbi.nlm.nih.gov/pubchem/patent/JP-2006521371-A
priorityDate 1991-11-21^^<http://www.w3.org/2001/XMLSchema#date>
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