http://rdf.ncbi.nlm.nih.gov/pubchem/patent/JP-H07252287-A

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assignee http://rdf.ncbi.nlm.nih.gov/pubchem/patentassignee/MD5_52a65b677bbedbe7bf090dd556a7cc43
classificationIPCInventive http://rdf.ncbi.nlm.nih.gov/pubchem/patentipc/C07F17-00
filingDate 1994-03-14^^<http://www.w3.org/2001/XMLSchema#date>
inventor http://rdf.ncbi.nlm.nih.gov/pubchem/patentinventor/MD5_40969ed865a3293626a7d1f14902e176
http://rdf.ncbi.nlm.nih.gov/pubchem/patentinventor/MD5_af44b5d552db83cdd3e339b46670d867
http://rdf.ncbi.nlm.nih.gov/pubchem/patentinventor/MD5_382648e5fca6b6e3855fdd747d4eaef2
publicationDate 1995-10-03^^<http://www.w3.org/2001/XMLSchema#date>
publicationNumber JP-H07252287-A
titleOfInvention Method for producing metallocene compound
abstract (57) [Summary] (Modified) [Configuration] Formulas (1) and (3) (R 1 , R 2 , R 3 and R 4 are C 1 -C 4 alkyl, trialkylsilyl, phenyl, hydrogen, R 1 , R 2 , R 3 , At least one R 4 may be a group different from each other, not hydrogen. Cp represents a 1,3-cyclopentadiene ring) and a substituted cyclopentadiene represented by the formula (3) is reacted with dimethyldihalosilane in the presence of a metal salt-type base and a metal ion trapping agent. Dimethyl bis (substituted cyclopentadienyl) silane is prepared, the silane is dissolved in a solvent and a strong base is added to prepare the product [A], while the transition metal halogen compound is dispersed in an inert solvent. Then, a complexing solution [B] obtained by dissolving or suspending in an ether solvent is prepared, and the product [A] and the complexing solution [B] are prepared. React with and formula (5) A silicon-bridged metallocene compound represented by is produced. [Effect] Decomposition and coagulation in the transition metal salt / solvent system solution formation are prevented, and the reaction time can be shortened, side reactions can be suppressed, and the yield can be improved.
priorityDate 1994-03-14^^<http://www.w3.org/2001/XMLSchema#date>
type http://data.epo.org/linked-data/def/patent/Publication

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