http://rdf.ncbi.nlm.nih.gov/pubchem/patent/JP-H11312681-A

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filingDate 1998-04-30^^<http://www.w3.org/2001/XMLSchema#date>
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publicationDate 1999-11-09^^<http://www.w3.org/2001/XMLSchema#date>
publicationNumber JP-H11312681-A
titleOfInvention Semiconductor device and manufacturing method thereof
abstract (57) [PROBLEMS] To prevent corrosion of Al wiring when an insulating film containing fluorine is used. SOLUTION: Al2 is etched on a silicon substrate 1 using a photoresist 5 as a mask to form an Al wiring 2a (a) and (b). In this step, a native oxide film 6 is formed on the side wall of the Al wiring 2a (b). Natural oxide film 6 Is formed at the same time as Al etching, so that elements such as chlorine gas during etching and carbon in the photoresist material are mixed into the aluminum oxide, and a high-quality aluminum oxide film having a uniform composition is formed. Absent. Therefore, the natural oxide film 6 on the side wall is removed by physical etching using an inert gas such as argon or reactive etching such as BCl 3 under a reduced pressure or an atmosphere containing little oxygen (c). Subsequently, oxygen or oxygen radicals are introduced without breaking vacuum to form a high-quality aluminum oxide film 6a on the Al side wall (d). A fluorine-containing insulating film 7 is formed on the barrier of the high-quality aluminum oxide film 6a (f).
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