http://rdf.ncbi.nlm.nih.gov/pubchem/patent/JP-WO2004099118-A1

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classificationIPCInventive http://rdf.ncbi.nlm.nih.gov/pubchem/patentipc/C07C211-28
http://rdf.ncbi.nlm.nih.gov/pubchem/patentipc/C07C209-54
http://rdf.ncbi.nlm.nih.gov/pubchem/patentipc/C07C219-20
http://rdf.ncbi.nlm.nih.gov/pubchem/patentipc/C07C209-52
filingDate 2004-05-10^^<http://www.w3.org/2001/XMLSchema#date>
publicationDate 2006-07-13^^<http://www.w3.org/2001/XMLSchema#date>
publicationNumber JP-WO2004099118-A1
titleOfInvention Production of terpenes
abstract Terpenes into which a trans-type vinyl group (for example, an isoprene unit) has been introduced are synthesized by an aza-Claisen reaction that proceeds at a much lower temperature than before. A quaternary ammonium salt having a quaternary ammonium group on the carbon atom bonded to the vinyl group is synthesized. When a base is allowed to act on this, nitrogen ylide is produced as an intermediate. This rearrangement produces a trans-type vinyl group and at the same time an iminium salt. Thereafter, the iminium salt is reduced to obtain an amine. This reaction adds a trans-type vinyl group. This reaction proceeds at low temperatures. By repeating these reactions, useful terpenes can be synthesized.
priorityDate 2003-05-12^^<http://www.w3.org/2001/XMLSchema#date>
type http://data.epo.org/linked-data/def/patent/Publication

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