http://rdf.ncbi.nlm.nih.gov/pubchem/patent/JP-WO2004099118-A1
Outgoing Links
Predicate | Object |
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classificationCPCInventive | http://rdf.ncbi.nlm.nih.gov/pubchem/patentcpc/C07C209-52 |
classificationIPCInventive | http://rdf.ncbi.nlm.nih.gov/pubchem/patentipc/C07C211-28 http://rdf.ncbi.nlm.nih.gov/pubchem/patentipc/C07C209-54 http://rdf.ncbi.nlm.nih.gov/pubchem/patentipc/C07C219-20 http://rdf.ncbi.nlm.nih.gov/pubchem/patentipc/C07C209-52 |
filingDate | 2004-05-10^^<http://www.w3.org/2001/XMLSchema#date> |
publicationDate | 2006-07-13^^<http://www.w3.org/2001/XMLSchema#date> |
publicationNumber | JP-WO2004099118-A1 |
titleOfInvention | Production of terpenes |
abstract | Terpenes into which a trans-type vinyl group (for example, an isoprene unit) has been introduced are synthesized by an aza-Claisen reaction that proceeds at a much lower temperature than before. A quaternary ammonium salt having a quaternary ammonium group on the carbon atom bonded to the vinyl group is synthesized. When a base is allowed to act on this, nitrogen ylide is produced as an intermediate. This rearrangement produces a trans-type vinyl group and at the same time an iminium salt. Thereafter, the iminium salt is reduced to obtain an amine. This reaction adds a trans-type vinyl group. This reaction proceeds at low temperatures. By repeating these reactions, useful terpenes can be synthesized. |
priorityDate | 2003-05-12^^<http://www.w3.org/2001/XMLSchema#date> |
type | http://data.epo.org/linked-data/def/patent/Publication |
Incoming Links
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