http://rdf.ncbi.nlm.nih.gov/pubchem/patent/RU-2265586-C2

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filingDate 2001-04-27^^<http://www.w3.org/2001/XMLSchema#date>
grantDate 2005-12-10^^<http://www.w3.org/2001/XMLSchema#date>
inventor http://rdf.ncbi.nlm.nih.gov/pubchem/patentinventor/MD5_22fb941d3d89fdd5a978e4efef111f79
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publicationDate 2005-12-10^^<http://www.w3.org/2001/XMLSchema#date>
publicationNumber RU-2265586-C2
titleOfInvention Method for preparing phenol and acetone by acid-catalyzed cleavage of cumyl hydroperoxide followed by thermal treatment and reactor for realizing method
abstract FIELD: organic chemistry, chemical technology. n SUBSTANCE: invention relates to a method for preparing phenol and acetone by acid-catalyzed cleavage of cumyl hydroperoxide. Method involves preliminary heating the reaction mixture to temperature above 100°C and then for thermal treatment of product heat in exothermic reaction is used, mainly the cleavage reaction of cumyl hydroperoxide that presents in the concentration from 5 to 10 wt.-%. The preferable residual content of dicumyl hydroxide in thermally treated product is 0.01-0.05 wt.-%. Stages in cleavage of cumyl hydroperoxide and the following thermal treatment can be carried out in a single reactor with two zones among that one zone is fitted with a device for heat removing and another zone has a feature of the flow-type pipe. Reactor is equipped by a device for circulation of part of product from thermal treatment zone to a feeding line for decomposition of product. Method provides improving energetic indices of process due to optimal consumption of heat energy in maintaining high selectivity of the decomposition process. n EFFECT: improved preparing method. n 15 cl, 3 dwg
priorityDate 2000-05-03^^<http://www.w3.org/2001/XMLSchema#date>
type http://data.epo.org/linked-data/def/patent/Publication

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