http://rdf.ncbi.nlm.nih.gov/pubchem/patent/TW-494117-B

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filingDate 1997-09-19^^<http://www.w3.org/2001/XMLSchema#date>
grantDate 2002-07-11^^<http://www.w3.org/2001/XMLSchema#date>
inventor http://rdf.ncbi.nlm.nih.gov/pubchem/patentinventor/MD5_64cf337db605a1192b3efd3531d6e9f5
http://rdf.ncbi.nlm.nih.gov/pubchem/patentinventor/MD5_3b81772957c2269ec32f48086fdbdd4d
publicationDate 2002-07-11^^<http://www.w3.org/2001/XMLSchema#date>
publicationNumber TW-494117-B
titleOfInvention Process for improving polyamide, acrylic, aramid, cellulosic and polyester properties, and modified polymers produced thereby
abstract Methods are provided for treating polyester, polyamide, acrylic, aramid or cellulosic substrates to improve the uniformity of dyeing and to improve the hydrophilic, soil-release, odor-, mildew-, bacterial- and fungal- resistant properties of these substrates. A process for improving the fiber surface properties of polyester polymers, comprising the steps of: (a) contacting a polyester substrate with an aqueous monomer or monomer mixture; (b) slowly adding a polymerization initiator to said contacted polyester substrate heated to a temperature suitable for polymerization over a time period of greater than 3 minutes; and (c) polymerizing said monomers on said contacted polyester substrate to form a surface modified polyester substrate, wherein said monomer mixture comprises a water-soluble vinyl monomer and a cross-linking hydrophobic vinyl monomer, wherein said water-soluble vinyl monomer is selected from the group consisting of N,N'-methylenebisacrylamide, N,N'-(1,2-dihydroxyethylene)bisacrylamide, acrylamine, acrylic acid, 2-propyl-1-ol, crotonic acid, tetraethylene glycol diacrylate, vinylpyridine, methacrylic acid, methacrylamide, 4-methylolacrylamide, N-methyl-N-vinyl formamide, N-vinyl pyrrolidone, 3-methyl-N-vinyl pyrrolidone, 4-methyl-N-vinyl pyrrolidone, 5-methyl-N-vinyl pyrrolidone, maleic acid, vinyl oxyethylformamide, acrylonitrile, methacrylonitrile, methallylalcohol, acrylyl cyanide, styrene sulfonic acid and water-soluble salts of styrene sulfonic acid, wherein said cross-linking hydrophobic vinyl monomer is selected from the group consisting of bisphenol A dimethacrylate, ethylene glycol dimethacrylate, ethoxylated bisphenol A dimethacrylate, allyl acrylate, allyl methacrylate, 1,3-butylene glycol diacrylate, 1,3-butylene glycol dimethacrylate, 1,4-butanediol diacrylate, diallyl fumarate, diethylen glycol diacrylate, 2,2-dimethylpropane 1,3-diacrylate, 2,2-dimethylpropane 1,3-dimethacrylate, dipentaerythritol monohydroxypentaacrylate, ethoxylated bisphenol A diacrylate, 1,6-hexanediol diacrylate, 1,6-hexanediol dimethacrylate, pentaerythritol tetraacrylate, pentaerythritol triacrylate, pentaerythritol tetramethacrylate, trimethylolpropane triacrylate, tri-methylolpropane trimethacrylate, and tripropylene glycol diacrylate, wherein said polymerization initiator is added continuously or portion-wise over a time period ranging from 5 minutes to about 30 minutes, wherein said polymerization initiator is added to an aqueous solution of said water-soluble vinyl monomer in contact with said polyester substrate at a temperature of 80-100 DEG C, wherein said polymerizing is conducted at a pH of about 2-4, and wherein said polymerization initiator is a cationic initiator selected from the group consisting of 2,2'-azobis(N,N'-dimethyleneisobutyrylamidine) dihydrochloride, 2,2'-azobis(2-amidinopropane) dihydrochloride and 2,2'-azobis(N,N'-dimethylenebisisobutyrylamidine).
priorityDate 1996-09-20^^<http://www.w3.org/2001/XMLSchema#date>
type http://data.epo.org/linked-data/def/patent/Publication

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