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publicationDate 2019-04-02^^<http://www.w3.org/2001/XMLSchema#date>
publicationNumber US-10246387-B2
titleOfInvention Process for selectivating catalyst for producing paraxylene by methylation of benzene and/or toluene
abstract A process is described for producing paraxylene, in which an aromatic hydrocarbon feedstock comprising benzene and/or toluene is contacted with an alkylating reagent comprising methanol and/or dimethyl ether in an alkylation reaction zone under alkylation conditions in the presence of an alkylation catalyst to produce an alkylated aromatic product comprising xylenes. The alkylation catalyst comprises a molecular sieve having a Constraint Index ≤5, and the alkylation conditions comprise a temperature less than 500° C. The alkylation catalyst may be selectivated to produce a higher than equilibrium amount of paraxylene by using a molar ratio of alkylating agent to aromatic of at least 1:4.
priorityDate 2016-10-06^^<http://www.w3.org/2001/XMLSchema#date>
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