http://rdf.ncbi.nlm.nih.gov/pubchem/patent/US-2003040587-A1

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filingDate 2002-03-19^^<http://www.w3.org/2001/XMLSchema#date>
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publicationDate 2003-02-27^^<http://www.w3.org/2001/XMLSchema#date>
publicationNumber US-2003040587-A1
titleOfInvention Mid-range vinylidene content polyisobutylene polymer product and process for producing the same
abstract A relatively low molecular weight, mid-range vinylidene content PIB polymer product and a process for making the same. At least about 90% of the PIB molecules present in the product comprise alpha or beta position isomers. The vinylidene (alpha) isomer content of the product may range from 20% to 70% thereof and the content of tetra-substituted internal double bonds is very low, preferably less than about 5% and ideally less than about 1-2%. The midrange vinylidene content PIB polymer products are prepared by a liquid phase polymerization process conducted in a loop reactor at a temperature of at least 60° F. using a BF 3 /methanol catalyst complex and a contact time of no more than 4 minutes.
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