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filingDate 2002-02-20^^<http://www.w3.org/2001/XMLSchema#date>
inventor http://rdf.ncbi.nlm.nih.gov/pubchem/patentinventor/MD5_94fd75ac9f59315559be8f0944095ca8
http://rdf.ncbi.nlm.nih.gov/pubchem/patentinventor/MD5_28a1b1ce9f3d77c6d9ccfd7da236d8b6
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publicationDate 2004-06-10^^<http://www.w3.org/2001/XMLSchema#date>
publicationNumber US-2004110029-A1
titleOfInvention Asymmetric dendrimers
abstract Asymmetric dendrimers are disclosed. These are of two types (a) one which comprises a light emitting dendrimer having the formula: CORE-[DENDRITE 1 ] n [DENDRITE 2 ] m in which CORE represents an atom or group, n and m, which may be the same or different, each represent an integer of at least 1, each DENDRITE 1 , which may be the same or different when n is greater than 1, and each DENDRITE 1 , which may be the same or different when m is greater than 1, represent dendritic structures, at least one of said structures being fully conjugated and comprising aryl and/or heteroaryl groups and, optionally, vinyl and/or acetylenyl groups connected via sp 2 or sp hybridized carbon atoms of said ((hetero)aryl, vinyl and acetylenyl groups, and at least one branching point and/or link between the branching points in DENDRITE 1 being different from those in DENDRITE 2 , CORE terminating in the single bond which is connected to a sp 2 hybridized (ring) carbon atom of the first (hetero)aryl group to which more than one conjugated dendritic branch is attached, said ring carbon atom forming part of said fully conjugated DENDRITE 1 or DENDRITE 2 and CORE terminating at the single bond to the first branching point for the other of said DENDRITE 1 or DENDRITE 2 , at least one of the CORE, DENDRITE 1 and DENDRITE 2 being luminescent and (b) one which comprises a light emitting dendrimer having the formula: CORE-[DENDRITE] n in which CORE represents an atom or group, n represents an integer of at least 1, each DENDRITE, which may be the same or different, represents an inherently at least partially conjugated dendritic structure which comprises aryl and/or heteroaryl and, optionally, vinyl and/or acetylenyl groups, connected via sp 2 or sp hybridized carbon atoms of said (hetero)aryl, vinyl and acetylenyl groups, and wherein the links between at least one pair of adjacent branching points in said DENDRITE are different such that if two links are to be regarded as different then one said link must comprise at least one aryl, heteroaryl, vinyl or acetylenyl group which is not present in the other of said two links, CORE terminating in the single bond which is connected to a sp 2 hybridized (ring) carbon atom of the first (hetero)aryl group to which more than one dendritic branch is attached, said ring carbon atom forming part of said DENDRITE, the CORE and/or DENDRITE being luminescent.
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