abstract |
A polymerization medium having small ozone depletion potential and small global warming potential and having a small chain transfer constant is used, to efficiently produce a fluoropolymer having a high molecular weight and having excellent heat resistance, solvent resistance, chemical resistance, etc. n A process for producing a fluoropolymer, which comprises polymerizing a fluoromonomer having a carboxylic acid type functional group and a fluoroolefin using a hydrofluorocarbon as a medium, wherein the hydrofluorocarbon as the medium has 4 to 10 carbon atoms and has a ratio (molar basis) of the number of hydrogen atoms/the number of fluorine atoms (H/F ratio) of from 0.05 to 20. |