http://rdf.ncbi.nlm.nih.gov/pubchem/patent/US-2013096353-A1

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publicationDate 2013-04-18^^<http://www.w3.org/2001/XMLSchema#date>
publicationNumber US-2013096353-A1
titleOfInvention Process for producing fluoroalkyl iodide
abstract To provide a process for producing a fluoroalkyl iodide, whereby the selectivity for a fluoroalkyl iodide having a desired degree of polymerization is high and the productivity is high. A process for producing a fluoroalkyl iodide (2) represented by R f CF 2 CF 2 I (wherein R f is a fluoroalkyl group having at most 4 carbon atoms), which comprises reacting a fluoroalkyl iodide (1) represented by R f I with tetrafluoroethylene in the presence of a radical initiator, wherein a first reaction step of supplying and reacting tetrafluoroethylene and a radical initiator to the fluoroalkyl iodide (1), is followed by repeating (n−1) times (provided that n is an integer of at least 3) a subsequent reaction step of supplying and reacting a radical initiator, or a radical initiator and tetrafluoroethylene, to a reaction mixture (1) formed in the first reaction step.
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