http://rdf.ncbi.nlm.nih.gov/pubchem/patent/US-4103092-A

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assignee http://rdf.ncbi.nlm.nih.gov/pubchem/patentassignee/MD5_3a5173a7d063a9f70ca7b5e86fc23863
classificationCPCInventive http://rdf.ncbi.nlm.nih.gov/pubchem/patentcpc/C09B44-02
classificationIPCInventive http://rdf.ncbi.nlm.nih.gov/pubchem/patentipc/C09B44-02
filingDate 1975-07-14^^<http://www.w3.org/2001/XMLSchema#date>
grantDate 1978-07-25^^<http://www.w3.org/2001/XMLSchema#date>
inventor http://rdf.ncbi.nlm.nih.gov/pubchem/patentinventor/MD5_2a6e1d007555bb1a5fc623fb6c5aab1d
http://rdf.ncbi.nlm.nih.gov/pubchem/patentinventor/MD5_668124d0dc7e2d6cb0ea5424a809e10c
publicationDate 1978-07-25^^<http://www.w3.org/2001/XMLSchema#date>
publicationNumber US-4103092-A
titleOfInvention Water-soluble quaternary ammonium non-heterocyclic azo dyestuffs
abstract Water-soluble cationic dyestuffs of the formulae ##STR1## WHEREIN R 0 is hydrogen, lower-alkyl or hydroxy-lower-alkyl; n R 1 is lower-alkyl, lower-alkenyl or hydroxy-lower-alkyl; n R 2 is lower-alkyl, lower-alkenyl, hydroxy-lower-alkyl or -(lower-alkylene)-NR 0 Y or R 1 and R 2 together with the nitrogen atom, are pyrrolidino, piperidino or 4-lower-alkanoyl piperazino; n Y is hydrogen or ##STR2## wherein R is hydrogen, lower-alkyl, lower-alkenyl, phenyl or phenyl-lower-alkyl; n A is a member selected from the group consisting of an aromatic azo dyestuff residue attached to the quaternary ammonium nitrogen atom through a lower-alkylene bridge. n k is a small integer whose value is dependent on the nature or A such that it has a range from one to two; n R 8 is lower-alkyl, lower-alkenyl or hydroxy-lower-alkyl; n R 9 is lower-alkyl, hydroxy-lower-alkyl or NH 2 ; n R 10 is lower-alkyl or lower-alkenyl; n A 1 is an aromatic azo dyestuff residue attached to the quaternary ammonium nitrogen atom through a lower-alkylene bridge; n g is a small integer whose value is dependent on the nature of A 1 such that it has a range from one to two; n R 8' is lower-alkyl; n R 9' is lower-alkyl, lower-alkenyl or hydroxy-lower-alkyl; n R 10' is lower-alkyl, lower-alkenyl or hydroxy-lower-alkyl or R 9' and R 10' together with the nitrogen atom are morpholino; n A 2 is an aromatic azo dyestuff residue attached to the quaternary ammonium nitrogen atom through a lower-alkylene bridge; n h is a small integer whose value is dependent on the nature of A 2 such that it has a range from one to two; and n An is an anion n Are particularly useful for coloring natural fibers, synthetic fiber-forming materials and cellulosic materials. These dyes dye cotton and paper various shades of stable yellows, reds and oranges. The dyeing from these dyes on paper are less prone to bleed and have a high degree of color discharge when bleached with hypochlorite or chlorine bleaches.
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