abstract |
A method of producing a silver halide photographic emulsion including the step of: reacting a water-soluble silver salt and at least one water-soluble halide salt containing chloride in aqueous solution in the presence of at least one compound represented by formulae (I) or (II): <IMAGE> (I) <IMAGE> (II) wherein A1, A2, A3 and A4, which may be the same or different, each represents a nonmetallic atomic group necessary for forming a substituted or unsubstituted heterocyclic ring; B represents a divalent linking group; R1 and R2, which may be the same or different, each represents an alkyl group; X represents an anion necessary for charge balance; m is 0 or 1; and n is 0 or 1; to form light-sensitive silver halide grains having a silver chloride content of at least 50 mol %, selected from octahedral grains, tetradecahedral grains and tablular grains, wherein at least 30% of the surface area of said light-sensitive silver halide grains is composed of (111) planes. The high chloride silver halide emulsions are suitable for rapid development processing with reduced fogging. |