| abstract |
Metal-containing, shaped, polymeric, tertiary and/or secondary organosiloxane amine compounds are introduced which contain the metals Pd, Pt, Ru, Rh individually or in combination as well as optional promotors and/or moderators. The organosiloxane amine functioning as carrier for the metals contains the units <IMAGE> and/or units <IMAGE> (II) in which R1 to R5 are a group <IMAGE> (III) with R6 as a double-bonded group bound to N and Si (e.g. an alkylene group) and X is an amine group such as <IMAGE> The carrier substance can be cross-linked with cross-linking agents containing Si, Ti, Zr or Al. The metal-containing product is spherical in form and is defined by the parameters of sphere diameter, specific surface and pore volume as well as bulk density. A method of production is disclosed which can be carried out in several variants as well as the use of the metal-containing product as catalyst for hydrogenation reactions and oxidation reactions. |