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filingDate 1999-12-24^^<http://www.w3.org/2001/XMLSchema#date>
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inventor http://rdf.ncbi.nlm.nih.gov/pubchem/patentinventor/MD5_714bdd0b918bc9df5f44c1f57ab58a6f
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publicationDate 2002-06-25^^<http://www.w3.org/2001/XMLSchema#date>
publicationNumber US-6410797-B1
titleOfInvention Process for the production of ketoisophorone derivatives and equipment therefor
abstract In the presence of an oxidizing catalyst, a beta-isophorone derivative of the following formula (1) is oxidized in a solvent substantially from acid components (organic carboxylic acids) to form a ketoisophorone derivative of the following formula (2). The amount of the acid component in the solvent is 0 to 4,000 ppm (weight basis). The oxidizing catalyst is a complex salt of a transition metal and an N,N'-disalicylidenediamine. In the reaction, a cyclic base may further be employed as a co-catalyst. The solvent separated from the reaction mixture may be recycled to the oxidation reaction after removal of the acid component contained therein.
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