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publicationDate 2002-11-19^^<http://www.w3.org/2001/XMLSchema#date>
publicationNumber US-6482764-B1
titleOfInvention Method for producing a supported catalyst for ethylene polymerization and ethylene/α-olefin copolymerization
abstract A method for producing a supported catalyst useful in polymerization of ethylene and copolymerization of ethylene and alpha-olefin is disclosed. The method includes treating the magnesium-containing carrier with a titanium compound containing oxygen atom(s), wherein said carrier is obtained by reaction of an organomagnesium compound of the structure of MgPh2.nMgCl2.mR2O (n=0.37~0.7; m>=1; R20=ether; Ph=phenyl) with an organic chloride compound in a mole ratio of organic chloride compound/Mg>=0.5, at -20~80° C. In one embodiment, the organic chloride compound may be carbon tetrachloride. A specific catalyst is provided whose activity is low in the beginning but slowly rises to a sufficient degree as the process of polymerization progresses, the polymer produced with the use of said catalyst having high bulk density, a well adjusted particle size distribution, and a narrow molecular weight distribution.
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