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filingDate 2002-05-20^^<http://www.w3.org/2001/XMLSchema#date>
grantDate 2004-02-24^^<http://www.w3.org/2001/XMLSchema#date>
inventor http://rdf.ncbi.nlm.nih.gov/pubchem/patentinventor/MD5_05abfc862b688e5a6cbb728c4ad44271
http://rdf.ncbi.nlm.nih.gov/pubchem/patentinventor/MD5_d1b2c7748aa6e80d7cabf4c285c39893
publicationDate 2004-02-24^^<http://www.w3.org/2001/XMLSchema#date>
publicationNumber US-6696536-B2
titleOfInvention ABA triblock and diblock copolymers and methods of preparing the same
abstract The invention discloses a method for preparing a triblock copolymer of the formula:comprising:(a) contacting a cycloalkene with a chain transfer agent of the formula:in the presence of a metal carbene metathesis catalyst to form a telechelic polymer; and(d) contacting the telechelic polymer with an alkene of the formulain the presence of an ATRP organometallic catalystwherein n and m are integers; Z is an ATRP initiator and -Y=Y- is an alkenyl group; and, R' is selected from the group consisting of aryl, nitrile and C1-C20 carboxylate, wherein R' is substituted or unsubstituted. The invention also discloses a method for preparing a diblock copolymer. In addition, the invention encompasses a triblock copolymer having no 1,2-PBD structure in the PBD portion of the copolymer.
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