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publicationNumber US-7659435-B2
titleOfInvention Process for the preparation of 1,1,1,3,3-pentafluoropropane and 1,1,1,2,3-pentafluoropropane
abstract A process is disclosed for the manufacture of CF 3 CH 2 CHF 2 and CF 3 CHFCH 2 F. The process involves (a) reacting hydrogen fluoride, chlorine, and at least one halopropene of the formula CX 3 CCl═CClX (where each X is independently F or Cl) to produce a product including both CF 3 CCl 2 CClF 2 and CF 3 CClFCCl 2 F; (b) reacting CF 3 CCl 2 CClF 2 and CF 3 CClFCCl 2 F produced in (a) with hydrogen to produce a product including both CF 3 CH 2 CHF 2 , and CF 3 CHFCH 2 F; and (c) recovering CF 3 CH 2 CHF 2 and CF 3 CHFCH 2 F from the product produced in (b). In (a), the CF 3 CCl 2 CF 3 and CF 3 CClFCClF 2 are produced in the presence of a chlorofluorination catalyst including (i) a crystalline alpha-chromium oxide where at least 0.05 atom % of the chromium atoms in the alpha-chromium oxide lattice are replaced by divalent copper, and/or (ii) a chromium-containing composition of (i) which has been treated with a fluorinating agent.
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