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publicationDate 2010-08-24^^<http://www.w3.org/2001/XMLSchema#date>
publicationNumber US-7781142-B2
titleOfInvention Copolymer and top coating composition
abstract A resin composition for forming a top coat which can be formed on a photoresist film without causing intermixing with the photoresist film, can maintain a stable film coating which is not eluted into a medium during immersion lithography, does not impair pattern profiles during dry exposure (which is not immersion lithography), and can be easily dissolved in an alkaline developer. The resin is a copolymer which comprises at least one recurring unit (I) selected from the group consisting of a recurring unit having a group shown by the following formula (1), a recurring unit having a group shown by the following formula (2), and a recurring unit having a carboxyl group, and a recurring unit (II) having a sulfo group, the copolymer having a weight average molecular weight determined by gel permeation chromatography of 2,000 to 100,000, n nwherein at least one of R 1 and R 2 is a fluoroalkyl group having 1 to 4 carbon atoms and R 3 in the formula (2) represents a fluoroalkyl group having 1 to 20 carbon atoms.
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