| Predicate |
Object |
| assignee |
http://rdf.ncbi.nlm.nih.gov/pubchem/patentassignee/MD5_a37a0938c7d9583dce17b758a0c3f044 |
| classificationCPCAdditional |
http://rdf.ncbi.nlm.nih.gov/pubchem/patentcpc/B01J2231-643
http://rdf.ncbi.nlm.nih.gov/pubchem/patentcpc/B01J2531-827
http://rdf.ncbi.nlm.nih.gov/pubchem/patentcpc/B01J2531-822
http://rdf.ncbi.nlm.nih.gov/pubchem/patentcpc/B01J2531-821
http://rdf.ncbi.nlm.nih.gov/pubchem/patentcpc/C07B2200-07
http://rdf.ncbi.nlm.nih.gov/pubchem/patentcpc/B01J2231-645 |
| classificationCPCInventive |
http://rdf.ncbi.nlm.nih.gov/pubchem/patentcpc/C07C51-36
http://rdf.ncbi.nlm.nih.gov/pubchem/patentcpc/C07C67-303
http://rdf.ncbi.nlm.nih.gov/pubchem/patentcpc/C07C231-12
http://rdf.ncbi.nlm.nih.gov/pubchem/patentcpc/B01J31-1875
http://rdf.ncbi.nlm.nih.gov/pubchem/patentcpc/C07F17-02
http://rdf.ncbi.nlm.nih.gov/pubchem/patentcpc/B01J31-2495
http://rdf.ncbi.nlm.nih.gov/pubchem/patentcpc/C07F9-5022
http://rdf.ncbi.nlm.nih.gov/pubchem/patentcpc/C07F15-008
http://rdf.ncbi.nlm.nih.gov/pubchem/patentcpc/C07C213-02 |
| classificationIPCInventive |
http://rdf.ncbi.nlm.nih.gov/pubchem/patentipc/C07F9-53
http://rdf.ncbi.nlm.nih.gov/pubchem/patentipc/C07F15-02
http://rdf.ncbi.nlm.nih.gov/pubchem/patentipc/B01J31-18
http://rdf.ncbi.nlm.nih.gov/pubchem/patentipc/C07C69-34 |
| filingDate |
2007-05-23^^<http://www.w3.org/2001/XMLSchema#date> |
| grantDate |
2011-08-30^^<http://www.w3.org/2001/XMLSchema#date> |
| inventor |
http://rdf.ncbi.nlm.nih.gov/pubchem/patentinventor/MD5_2826db1aec735fdaa80d87f33c0309e9
http://rdf.ncbi.nlm.nih.gov/pubchem/patentinventor/MD5_8f10514ab970713c8aca4d45d8999261
http://rdf.ncbi.nlm.nih.gov/pubchem/patentinventor/MD5_32569d90d5ba5ee564ed50847cc2b82b
http://rdf.ncbi.nlm.nih.gov/pubchem/patentinventor/MD5_722f3b1a76315bbea5620edceccf9533
http://rdf.ncbi.nlm.nih.gov/pubchem/patentinventor/MD5_2a53a4b47df03ec0db01b05520716d5c
http://rdf.ncbi.nlm.nih.gov/pubchem/patentinventor/MD5_1ce4c4d22b5c81d4da345eff94007f46 |
| publicationDate |
2011-08-30^^<http://www.w3.org/2001/XMLSchema#date> |
| publicationNumber |
US-8008529-B2 |
| titleOfInvention |
Chiral ligands used in transition metal catalysts for asymmetric addition reactions especially hydrogenation |
| abstract |
Ligands of the formula (I) secondary phosphine-Q-P(═O)HR 1 (I) in the form of mixtures of diastereomers or pure diastereomers, in which secondary phosphine is a secondary phosphine group with hydrocarbon radicals or heterohydrocarbon radicals as substituents; Q is a bivalent bisaryl or bisheteroaryl radical with an axial chiral centre to which the two phosphorus atoms are bonded in the ortho positions to the bisaryl or bisheteroaryl bridge bond, or Q is a bivalent ferrocenyl radical with a planar chiral centre or without a planar chiral centre, to which the phosphorus atom of the secondary phosphine is bonded directly or via a C 1 -C 4 -carbon chain to a cyclopentadienyl ring, the —P*(═O)HR 1 group is bonded either on the same cyclopentadienyl ring in ortho position to the bonded secondary phosphine or on the other cyclopentadienyl ring; P* is a chiral phosphorus atom, and R 1 is a hydrocarbon radical, a heterohydrocarbon radical or a ferrocenyl radical, where R 1 is a ferrocenyl radical with a planar chiral centre when Q is a ferrocenyl radical without a planar chiral centre. Metal complexes of these ligands are homogeneous catalysts for asymmetric addition reactions, particularly hydrogenations. |
| priorityDate |
2006-05-23^^<http://www.w3.org/2001/XMLSchema#date> |
| type |
http://data.epo.org/linked-data/def/patent/Publication |