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filingDate 2014-02-26^^<http://www.w3.org/2001/XMLSchema#date>
grantDate 2017-10-10^^<http://www.w3.org/2001/XMLSchema#date>
inventor http://rdf.ncbi.nlm.nih.gov/pubchem/patentinventor/MD5_b3276620f5c8aedeebdff7fba71969ac
http://rdf.ncbi.nlm.nih.gov/pubchem/patentinventor/MD5_44744177d4a49114f0db46519a92aacc
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publicationDate 2017-10-10^^<http://www.w3.org/2001/XMLSchema#date>
publicationNumber US-9782762-B2
titleOfInvention Substituted mononuclear ruthenium complexes for catalysis of synthetic organic reactions
abstract Provided is a mononuclear ruthenium complex that comprises a ruthenium-silicon bond that is represented by formula (1) and that exhibits excellent catalyst activity in each of a hydrosilylation reaction, a hydrogenation reaction, and reduction of a carbonyl compound. n n n n n n n n n n In formula (1), R 1 -R 6 either independently represent an alkyl group, an aryl group, an aralkyl group or the like that may be substituted with a hydrogen atom or X, or represent a crosslinking substituent in which at least one pair comprising one of R 1 -R 3 and one of R 4 -R 6 is combined. X represents a halogen atom, an organoxy group, or the like. L represents a two-electron ligand other than CO and phosphine. When a plurality of L are present, the plurality of L may be the same as or different from each other. When two L are present, the two L may be bonded to each other. n and m independently represent an integer of 1 to 3 with the stipulation that n+m equals 3 or 4.
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