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filingDate 2014-09-19^^<http://www.w3.org/2001/XMLSchema#date>
grantDate 2018-03-20^^<http://www.w3.org/2001/XMLSchema#date>
inventor http://rdf.ncbi.nlm.nih.gov/pubchem/patentinventor/MD5_2ee02a37218ae0233a4187dc781cd33d
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publicationDate 2018-03-20^^<http://www.w3.org/2001/XMLSchema#date>
publicationNumber US-9920077-B2
titleOfInvention Amine substituted trisilylamine and tridisilylamine compounds and synthesis methods thereof
abstract Halogen free amine substituted trisilylamine and tridisilylamine compounds and a method of their preparation via de-hydrogenative coupling between the corresponding unsubstituted trisilylamines and amines catalyzed by transition metal catalysts is described. This new approach is based on the catalytic dehydrocoupling of a Si—H and a N—H moiety to form an Si—N containing compound and hydrogen gas. The process can be catalyzed by transition metal heterogenous catalysts such as Ru(0) on carbon, Pd(0) on MgO) as well as transition metal organometallic complexes that act as homogeneous catalysts. The —Si—N containing products are halide free. Such compounds can be useful for the deposition of thin films by chemical vapor deposition or atomic layer deposition of Si containing films.
priorityDate 2013-09-27^^<http://www.w3.org/2001/XMLSchema#date>
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