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filingDate 2000-02-14^^<http://www.w3.org/2001/XMLSchema#date>
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publicationDate 2000-08-24^^<http://www.w3.org/2001/XMLSchema#date>
publicationNumber WO-0048973-A2
titleOfInvention Methods for decomposing esters and purifying alcohols
abstract A tertiary butyl alcohol charge stock typically contaminated with from about 0.5 to about 2 wt.% of formates and peroxides, is passed through an oxygenates decomposition reactor containing a bed of a decomposition catalyst comprising rhodium, platinum, palladium or mixture thereof at a temperature of from about 100 to about 280 °C to decompose the peroxides and formates, and to dehydrate a portion of the tertiary butyl alcohol to form isobutylene and water to thereby form a non-corrosive tertiary butyl alcohol feedstock that is substantially free from formates that is suitable for reaction with methanol in a methyl tertiary butyl ether etherification reactor to form a non-corrosive methyl tertiary butyl ether etherification reaction product from which methyl tertiary butyl ether can be recovered.
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