http://rdf.ncbi.nlm.nih.gov/pubchem/patent/WO-0210116-A2

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filingDate 2001-07-19^^<http://www.w3.org/2001/XMLSchema#date>
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publicationDate 2002-02-07^^<http://www.w3.org/2001/XMLSchema#date>
publicationNumber WO-0210116-A2
titleOfInvention Process for the preparation of alkyl 1-methylcyclopropanecarboxylate
abstract Disclosed is a 4-step process for the preparation of alkyl esters of 1-methylcyclopropanecarboxylic acid which comprises the steps of (1) converting η-butyrolactone to α-methyl-η-butyrolactone; (2) converting the α-methyl-η-butyrolactone from step (1) to an alkyl 4-halo-2-methyl-butyrate; (3) producing a xylene solution of the alkyl 4-halo-2-methyl-butyrate; and (4) contacting the xylene solution of the alkyl 4-halo-2-methylbutyrate from step (3) with an alkali metal alkoxide under conditions to temperature and pressure which causes vaporization of (i) an alkanol as it is fomred and (ii) an alkyl 1-methylcyclopropanecarboxylate as it si formed from the alkyl 4-halo-2-methylbutyrate. Also disclosed are processes whereby the alkyl 1-methylcyclopropanecarboxylate, prepared as described above, is converted to 1-methylcyclopropylamine.
priorityDate 2000-08-01^^<http://www.w3.org/2001/XMLSchema#date>
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