| abstract |
Disclosed is a method for producing a fluorine-containing alkyl (meth)acrylate represented by the general formula (2) below. The method is characterized in that a fluorine-containing alcohol represented by the general formula (1) below, a (meth)acrylic acid and a sulfonic acid halide are reacted in the presence of a base containing at least one tertiary amine. Rf-(CH2)k-[-A-(CH2)l-]m-OH (1) (In the formula, Rf represents a perfluoroalkyl group having 1-21 carbon atoms; A represents S, SO or SO2; k represents 0, 1 or 2; l represents 1, 2 or 3; and m represents 0 or 1. In this connection, k = 0 and m = 0 do not occur at the same time. Rf-(CH2)k-[-A-(CH2)l-]m-OCOCR=CH2 (2) (In the formula, R represents a hydrogen atom or a methyl group.) |