http://rdf.ncbi.nlm.nih.gov/pubchem/patent/WO-2021088285-A1

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filingDate 2020-03-13^^<http://www.w3.org/2001/XMLSchema#date>
inventor http://rdf.ncbi.nlm.nih.gov/pubchem/patentinventor/MD5_8abe2c7b64a0a899232eaca6bd664d4d
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publicationDate 2021-05-14^^<http://www.w3.org/2001/XMLSchema#date>
publicationNumber WO-2021088285-A1
titleOfInvention Extraction system and extraction method for extracting lithium and boron by separating calcium from calcium-containing brine with secondary amide/alkyl alcohol composite solvent, and use of extraction method
abstract Disclosed are an extraction system and extraction method for extracting lithium and boron by separating calcium from a calcium-containing brine with a secondary amide/alkyl alcohol composite solvent and the use of the extraction method. In the extraction system, a secondary amide and an alkyl alcohol are contained and used as extractants for extracting lithium and boron, respectively, and composed of a single compound or a mixture of two or more compounds. The total number of carbon atoms in the molecules is 12-18 and 8-20, respectively. The freezing point of the extraction system is less than 0ºC. A single-stage or multi-stage countercurrent extraction is conducted under the conditions that the volume ratio of an organic phase to a brine phase is 1-10 : 1, the density of the brine is 1.30 to 1.56 g/cm3, the pH value of the brine is 0 to 7 and the temperature is 0 to 50℃, an aqueous phase with a low calcium-lithium ratio is obtained through back extraction, and lithium chloride, lithium carbonate, lithium hydroxide and boric acid are respectively obtained through concentration, impurity removal and preparation. The secondary amide of the present invention has a simple molecular structure, and the composite solvent improved by an alkyl alcohol can extract lithium and boron simultaneously. The multi-stage extraction rate is high, the back extraction is carried out with water, and the acid and alkali consumption is greatly reduced. The extraction separation flow is shortened, and the extraction system has little solution loss and is suitable for development of oilfield brine.
priorityDate 2019-11-08^^<http://www.w3.org/2001/XMLSchema#date>
type http://data.epo.org/linked-data/def/patent/Publication

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